Enantioseparation by capillary electrophoresis using ionic liquids as chiral selectors
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/39786DOI: 10.1080/10408347.2018.1439365
ISSN: 1040-8347
Date
2018Affiliation
Universidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química; Universidad de Alcalá. Departamento de Química Orgánica y Química InorgánicaBibliographic citation
Critical Reviews in Analytical Chemistry, 2018, v. 48, n. 6, p. 429-446
Keywords
Chiral ionic liquids
capillary electrophoresis
chiral analysis
enantioseparation
chiral selector
Description / Notes
doi: 10.1080/10408347.2018.1439365
Project
CTQ2016-76368-P (Spanish Ministry of Economy and Competitiveness (MINECO))
CCG2016/EXP-071 (University of Alcalá)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© Taylor & Francis
Access rights
info:eu-repo/semantics/openAccess
Abstract
Capillary electrophoresis is one of the most widely employed analytical techniques to achieve enantiomeric separations. In spite of the fact that there are many chiral selectors commercially available to perform enantioseparations by CE, one of the most relevant topics in this field is the search for new selectors capable of providing high enantiomeric resolutions. Chiral ionic liquids have interesting characteristics conferring them a high potential in chiral separations although only some of them are commercially available.The aim of this article is to review all the works published on the use of chiral ionic liquids as chiral selectors in the development of enantioselective methodologies by CE, covering the period of time from 2006 (when the first research work on this topic was published) to 2017. The use of chiral ionic liquids as sole chiral selectors, as chiral selectors in dual systems or as chiral ligands will be considered. This review also provides detailed analytical information on the experimental conditions used to carry outenantioseparations in different fields as well as on the separation mechanism involved.
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