New self-assembled one-dimensional nickel coordination polymers and hydrogen-bonded networks
Date
2003
Authors
Vujovic D.
Raubenheimer H.G.
Nassimbeni L.R.
Journal Title
Journal ISSN
Volume Title
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Abstract
Reaction of Ni(NCS)2 with aminobenzonitrile (ABN) isomers in solution gave rise to the formation of five coordination polymers of the general formula [Ni(NCS)2(ABN)2]n consisting of one-dimensional chains with adjacent nickel centres linked by bridging NCS- or ABN ligands. The compounds were characterised by single crystal X-ray diffraction, X-ray powder diffraction, infrared spectroscopy, thermogravimetry, differential scanning calorimetry and mass spectrometry.
Description
Keywords
Differential scanning calorimetry, Hydrogen bonds, Infrared spectroscopy, Isomers, Mass spectrometry, Nickel compounds, Self assembly, Single crystals, Thermogravimetric analysis, X ray powder diffraction, Aminobenzonitrile isomers, Nickel coordination polymers, Single crystal x ray diffraction, Interpenetrating polymer networks
Citation
Journal of the Chemical Society. Dalton Transactions
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