Design and preparation of [4,4′-bipyridine]-1,1′-diium trinitromethanide (BPDTNM) as a novel nanosized ionic liquid catalyst: application to the synthesis of 1-(benzoimidazolylamino)methyl-2-naphthols
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Título: | Design and preparation of [4,4′-bipyridine]-1,1′-diium trinitromethanide (BPDTNM) as a novel nanosized ionic liquid catalyst: application to the synthesis of 1-(benzoimidazolylamino)methyl-2-naphthols |
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Autor/es: | Yarie, Meysam | Zolfigol, Mohammad Ali | Baghery, Saeed | Alonso, Diego A. | Khoshnood, Abbas | Kalhor, Mehdi | Bayatd, Yadollah | Asgarid, Asiye |
Grupo/s de investigación o GITE: | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Nanosized ionic liquid catalyst | [4,4′-bipyridine]-1,1′-diium trinitromethanide (BPDTNM) | Synthesis | 1-(benzoimidazolylamino)methyl-2-naphthols |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 24-abr-2017 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | New Journal of Chemistry. 2017, 41: 4431-4440. doi:10.1039/C6NJ04074H |
Resumen: | In this work, the novel bifunctional nanosized ionic liquid catalyst [4,4′-bipyridine]-1,1′-diium trinitromethanide (BPDTNM) was designed, synthesized, and characterized by using FT-IR spectra, 1H and 13C NMR spectra, X-ray diffraction patterns (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), thermogravimetry (TG), derivative thermogravimetry (DTG) analysis, differential thermal analysis (DTA), and HPLC-mass spectroscopy. The synthesized nanosized catalyst was successfully applied to the synthesis of 1-(benzoimidazolylamino)methyl-2-naphthol derivatives via a straightforward one-pot three-component condensation reaction of 2-aminobenzimidazole, 2-naphthol, and a wide range of aromatic aldehydes under mild and solvent-free conditions. |
Patrocinador/es: | We thank Bu-Ali Sina University, the Iran National Science Foundation (INSF) (The Grant of Allameh Tabataba’i’s Award, Grant Number: BN093), National Elites Foundation, the University of Alicante (VIGROB-173), and the Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) for financial support to our research groups. |
URI: | http://hdl.handle.net/10045/66668 |
ISSN: | 1144-0546 (Print) | 1369-9261 (Online) |
DOI: | 10.1039/C6NJ04074H |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1039/C6NJ04074H |
Aparece en las colecciones: | INV - CESO - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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2017_Yarie_etal_NewJChem_final.pdf | Versión final (acceso restringido) | 3,11 MB | Adobe PDF | Abrir Solicitar una copia |
2017_Yarie_etal_NewJChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 2,09 MB | Adobe PDF | Abrir Vista previa |
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