WEKO3
アイテム
{"_buckets": {"deposit": "3b3d0a20-2e7b-4a22-8c1a-482492c59875"}, "_deposit": {"created_by": 2, "id": "10485", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "10485"}, "status": "published"}, "_oai": {"id": "oai:nagasaki-u.repo.nii.ac.jp:00010485", "sets": ["56"]}, "author_link": ["41637", "41635", "41633", "41632", "41634", "41636", "41638"], "item_2_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012-02-16", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "274", "bibliographicPageStart": "266", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{"bibliographic_title": "Beilstein Journal of Organic Chemistry"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "New fluorescent compounds, benzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides (3a-g), 2-amino-4-methylsulfanylbenzo[4,5]thieno[3,2-d]pyrimidine (6), and 2-amino-4-methylsulfanyl-7-methoxybenzo[4,5]furo[3,2-d]pyrimidine (7), were synthesized in good yields from heterocyclic ketene dithioacetals (1a-c) and guanidine carbonate (2a) or (S)-methylisothiourea sulfate (2b) in pyridine under reflux. Among the fused pyrimidine derivatives, compound 3c, which has an amino group at the 2-position and a benzylamino group at the 4-position of the pyrimidine ring, showed the strongest solid-state fluorescence. The absorption and emission properties of the compounds were quantitatively reproduced by a series of ab initio quantum-chemical calculations.", "subitem_description_type": "Abstract"}]}, "item_2_description_63": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Beilstein Journal of Organic Chemistry, 8, pp.266-274; 2012", "subitem_description_type": "Other"}]}, "item_2_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften"}]}, "item_2_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.3762/bjoc.8.28", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_13": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2012 Yokota et al; licensee Beilstein-Institut."}, {"subitem_rights": "This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.\nThe license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)"}]}, "item_2_source_id_8": {"attribute_name": "EISSN", "attribute_value_mlt": [{"subitem_source_identifier": "18605397", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yokota, Kenichirou"}], "nameIdentifiers": [{"nameIdentifier": "41632", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hagimori, Masayori"}], "nameIdentifiers": [{"nameIdentifier": "41633", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mizuyama, Naoko"}], "nameIdentifiers": [{"nameIdentifier": "41634", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishimura, Yasuhisa"}], "nameIdentifiers": [{"nameIdentifier": "41635", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujito, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "41636", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shigemitsu, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "41637", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tominaga, Yoshinori"}], "nameIdentifiers": [{"nameIdentifier": "41638", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-12-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "BJOC8_266.pdf", "filesize": [{"value": "2.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2500000.0, "url": {"label": "BJOC8_266.pdf", "url": "https://nagasaki-u.repo.nii.ac.jp/record/10485/files/BJOC8_266.pdf"}, "version_id": "97531186-f10b-44bf-8b9e-1b5cb5a82a0a"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Amino group", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Fluorescence", "subitem_subject_scheme": "Other"}, {"subitem_subject": "HOMO/LUMO", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pyrimidine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Solid-state", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis, solid-state fluorescence properties, and computational analysis of novel 2-aminobenzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis, solid-state fluorescence properties, and computational analysis of novel 2-aminobenzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides"}]}, "item_type_id": "2", "owner": "2", "path": ["56"], "permalink_uri": "http://hdl.handle.net/10069/28989", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-08-09"}, "publish_date": "2012-08-09", "publish_status": "0", "recid": "10485", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis, solid-state fluorescence properties, and computational analysis of novel 2-aminobenzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides"], "weko_shared_id": -1}
Synthesis, solid-state fluorescence properties, and computational analysis of novel 2-aminobenzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides
http://hdl.handle.net/10069/28989
http://hdl.handle.net/10069/28989aa501f3b-4a07-4e5f-9ff5-8561a25dc115
名前 / ファイル | ライセンス | アクション |
---|---|---|
BJOC8_266.pdf (2.5 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2012-08-09 | |||||
タイトル | ||||||
タイトル | Synthesis, solid-state fluorescence properties, and computational analysis of novel 2-aminobenzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Amino group | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Fluorescence | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | HOMO/LUMO | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Pyrimidine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Solid-state | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yokota, Kenichirou
× Yokota, Kenichirou× Hagimori, Masayori× Mizuyama, Naoko× Nishimura, Yasuhisa× Fujito, Hiroshi× Shigemitsu, Yasuhiro× Tominaga, Yoshinori |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | New fluorescent compounds, benzo[4,5]thieno[3,2-d]pyrimidine 5,5-dioxides (3a-g), 2-amino-4-methylsulfanylbenzo[4,5]thieno[3,2-d]pyrimidine (6), and 2-amino-4-methylsulfanyl-7-methoxybenzo[4,5]furo[3,2-d]pyrimidine (7), were synthesized in good yields from heterocyclic ketene dithioacetals (1a-c) and guanidine carbonate (2a) or (S)-methylisothiourea sulfate (2b) in pyridine under reflux. Among the fused pyrimidine derivatives, compound 3c, which has an amino group at the 2-position and a benzylamino group at the 4-position of the pyrimidine ring, showed the strongest solid-state fluorescence. The absorption and emission properties of the compounds were quantitatively reproduced by a series of ab initio quantum-chemical calculations. | |||||
書誌情報 |
Beilstein Journal of Organic Chemistry 巻 8, p. 266-274, 発行日 2012-02-16 |
|||||
出版者 | ||||||
出版者 | Beilstein-Institut Zur Forderung der Chemischen Wissenschaften | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18605397 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.3762/bjoc.8.28 | |||||
権利 | ||||||
権利情報 | © 2012 Yokota et al; licensee Beilstein-Institut. | |||||
権利 | ||||||
権利情報 | This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc) |
|||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Beilstein Journal of Organic Chemistry, 8, pp.266-274; 2012 |