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PbBr2薄膜を蒸着したCsBr結晶における固体化学反応の分光学的その場観測
http://hdl.handle.net/10098/1360
http://hdl.handle.net/10098/1360284bd1f2-7694-4d71-92eb-946db36dfc54
名前 / ファイル | ライセンス | アクション |
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BD00005569_001.pdf (1.1 MB)
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Item type | 研究報告書 / Research Paper(1) | |||||
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公開日 | 2007-12-27 | |||||
タイトル | ||||||
タイトル | PbBr2薄膜を蒸着したCsBr結晶における固体化学反応の分光学的その場観測 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | In Situ Optical Absorption and Reflection Spectroscopy of Solied State Chemical Reactions in PbBr2-Deposited CsBr Crystals | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
資源タイプ | research report | |||||
著者 |
松永, 敏宏
× 松永, 敏宏× 樋口, 聖× 斎藤, 忠昭× 近藤, 新一× 浅田, 拡志× 石金, 益夫× MATSUNAGA, M× HIGUCHI, S× SAITO, T× KONDO, S× ASADA, H× ISHIKANE, M |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The effect of annealing on PbBr2 films vacuum-evaporated onto 77K CsBr crystals has been investigated by in situ optical absorption and reflection spectroscopy. In the early stages of the annealing, the Pb2+ ions take part in the formation of Cs4PbBr6 crystallites, near the surface of the CsBr crystals, via the formation of CsPbBr3 by the chemical between PbBr2 and CsBr. The crystallites exhibit a novel absorption spectrum suggesting that the 6s and 6p states of the Pb2+ ions are strongly localized. On heavy annealing at a high temperature (680K) followed by a rapid cooling to room temperature, the Pb2+ -ion centers. Thus we have succeeded in obtaining CsBr crystals heavily doped with Pb2+ ions by using such a novel method. | |||||
書誌情報 |
遠赤外領域開発研究 巻 3, p. 204-214, 発行日 2002-03 |
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書誌レコードID | ||||||
識別子タイプ | NCID | |||||
関連識別子 | TD00005569 |