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Infrared Study on β-Radiolysis of [Co(en-d 4) 3]Cl 3・3T2O (en:ethylenediamine)
https://doi.org/10.15099/00006368
https://doi.org/10.15099/000063683b0301aa-83fe-4ea3-9caa-567326690742
名前 / ファイル | ライセンス | アクション |
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annual_report8-8.pdf (377.5 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-10-03 | |||||
タイトル | ||||||
タイトル | Infrared Study on β-Radiolysis of [Co(en-d 4) 3]Cl 3・3T2O (en:ethylenediamine) | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15099/00006368 | |||||
ID登録タイプ | JaLC | |||||
著者 |
Kanesaka, Isao
× Kanesaka, Isao× Nishimura, Hiroyuki× Kanamori, Kan× Kawai, Kiyoyasu |
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著者別名 | ||||||
姓名 | 金坂, 績 | |||||
著者別名 | ||||||
姓名 | 西村, 裕幸 | |||||
著者別名 | ||||||
姓名 | 金森, 寛 | |||||
著者別名 | ||||||
姓名 | 川井, 清保 | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | 赤外スペクトルによる[Co(en-d 4)_3]Cl_3・3T_2Oのβ放射線分解の研究 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | β-Radiolysis of [Co(en-d4)3]Cl3・3T2O was studied under a mild condition by means of infrared spectroscopy over a period of 8 months. The spectra became complex due to the appearance of many new bands in the initial process. This is explained in terms of the exchange reaction in hydrogen isotopes between water and ethylenediamine. It was found that ethylenediamine decomposed by ~50% in 100 days, forming ammonia coordinated to a Co2+ ion and an ammonium ion. On the other hand, a Co (Ⅲ) ammine complex, acetylene and so on were not found. A scheme for the β-radiolysis is proposed. | |||||
書誌情報 |
富山大学トリチウム科学センター研究報告 = Annual Report of Tritium Research Center, Toyama University 巻 8, p. 87-91, 発行日 1988 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0287-1408 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10100133 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 富山大学トリチウム科学センター | |||||
資源タイプ(DSpace) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article |