Hydride, halide, methyl, carbonyl, and chalcogenido derivatives of. permethylmolybdenocene
Cp-2*MoCl2 (CP* = C5Me5) is obtained via reaction of MoCl5 with a mixture of Cp*K and NaBH4 followed by treatment with CHCl3. Cp-2*MoCl2 provides access to a large variety of other permethylmolybdenocene complexes which include Cp-2*MoH2, Cp-2*MoMe2, Cp-2*MoCO, Cp-2*MoO, Cp-2*;Mo(Me)Cl, Cp-2*Mo(H)I, Cp-2*Mo(EPh)H (E = S, Se, Te), Cp-2*Mo(eta(2)-E-2) (E = S, Se, Te), Cp-2*Mo(eta(2)-E-4) (E = S, Se), Cp-2*Mo(OSiMe3)CN, Cp-2*Mo(NCS)(2), and Cp-2*Mo(N-3)(2). (c) 2006 Elsevier B.V. All rights reserved.
- Publisher
- ELSEVIER SCIENCE SA
- Issue Date
- 2006-06
- Language
- English
- Article Type
- Article
- Keywords
NUCLEAR MAGNETIC-RESONANCE; PI-CYCLOPENTADIENYL HYDRIDES; ANSA MOLYBDENOCENE COMPLEXES; COORDINATED THIOCYANATE; BOND-CLEAVAGE; C-H; TUNGSTENOCENE; ELIMINATION; REACTIVITY; HYDROGEN
- Citation
INORGANICA CHIMICA ACTA, v.359, no.9, pp.2942 - 2955
- ISSN
- 0020-1693
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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