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Título: | Oxidative versus Non-oxidative Decarboxylation of Amino Acids: Conditions for the Preferential Formation of Either Strecker Aldehydes or Amines in Amino Acid/Lipid-Derived Reactive Carbonyl Model Systems |
Autor: | Zamora, Rosario CSIC ORCID ; León, María Mercedes CSIC; Hidalgo, Francisco J. CSIC ORCID | Fecha de publicación: | 2015 | Editor: | American Chemical Society | Citación: | Journal of agricultural and food chemistry 63: 8037- 8043 (2015) | Resumen: | © 2015 American Chemical Society. Comparative formation of both 2-phenylethylamine and phenylacetaldehyde as a consequence of phenylalanine degradation by carbonyl compounds was studied in an attempt to understand if the amine/aldehyde ratio can be changed as a function of reaction conditions. The assayed carbonyl compounds were selected because of the presence in the chain of both electron-donating and electron-withdrawing groups and included alkenals, alkadienals, epoxyalkenals, oxoalkenals, and hydroxyalkenals as well as lipid hydroperoxides. The obtained results showed that the 2-phenylethylamine/phenylacetaldehyde ratio depended upon both the carbonyls and the reaction conditions. Thus, it can be increased using electron-donating groups in the chain of the carbonyl compound, small amounts of carbonyl compound, low oxygen content, increasing the pH, or increasing the temperature at pH 6. Opposed conditions (use of electron-withdrawing groups in the chain of the carbonyl compound, large amounts of carbonyl compound, high oxygen contents, low pH values, and increasing temperatures at low pH values) would decrease the 2-phenylethylamine/phenylacetaldehyde ratio, and the formation of aldehydes over amines in amino acid degradations would be favored. | URI: | http://hdl.handle.net/10261/123994 | DOI: | 10.1021/acs.jafc.5b02619 | Identificadores: | doi: 10.1021/acs.jafc.5b02619 issn: 1520-5118 |
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