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Título: | Coming across a novel copper oxide 2D framework during the oxidation of Cu(111) |
Autor: | Matencio, Sonia CSIC; Barrena, Esther CSIC ORCID; Ocal, Carmen CSIC ORCID | Fecha de publicación: | 28-dic-2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | Physical Chemistry Chemical Physics 18(48): 33303-33309 (2016) | Resumen: | Two dimensional copper oxides obtained on Cu(111) by air-enriched argon sputtering plus annealing have been measured at room temperature by means of scanning tunneling microscopy (STM) and atomic force microscopy (AFM) under ultra-high vacuum (UHV) conditions. Depending on the oxygen content different oxide frameworks and diverse stoichiometric metal/oxide interfaces exist. In particular, we report on a novel open honeycomb structure with a large unit cell which is modeled as a two dimensional network made out of Cu3O units. This lattice coexists with other oxide structures richer in oxygen and is suggested to develop towards these denser phases by oxygen incorporation. | Versión del editor: | http://dx.doi.org/10.1039/C6CP07134A | URI: | http://hdl.handle.net/10261/141877 | DOI: | 10.1039/C6CP07134A | ISSN: | 1463-9076 |
Aparece en las colecciones: | (ICMAB) Artículos |
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PCCP_2016_Matencio_postprint.pdf | 2,55 MB | Adobe PDF | Visualizar/Abrir |
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