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Título: | Direct X-ray scattering evidence for metal-metal interactions in solution at the molecular level |
Autor: | Cebollada, Andrea CSIC; Vellé, Alba CSIC; Iglesias, Manuel CSIC ORCID; Fullmer, Lauren B.; Goberna-Ferrón, Sara CSIC ORCID; Nyman, May; Sanz Miguel, Pablo J. CSIC ORCID | Palabras clave: | NMR spectroscopy Small-angle X-ray scattering Silver Metal–metal interactions Carbene ligands |
Fecha de publicación: | 2015 | Editor: | Wiley-VCH | Citación: | Angewandte Chemie International Edition 54(43): 12762-12766 (2015) | Resumen: | The study of the aggregation of small molecules in solution induced by metallophilic interactions has been traditionally performed by spectroscopic methods through identification of chemical changes in the system. Herein we demonstrate the use of SAXS (small-angle X-ray scattering) to identify structures in solution, taking advantage of the excellent scattering intensity of heavy metals which have undergone association by metallophilic interactions. An analysis of the close relationship between solid-state and solution arrangements of a dynamic [Ag2(bisNHC)2]2+ (NHC=N-heterocyclic carbene) system, and how they are complementary to each other, is reported.. | URI: | http://hdl.handle.net/10261/154663 | DOI: | 10.1002/anie.201505736 | Identificadores: | doi: 10.1002/anie.201505736 e-issn: 1521-3773 issn: 1433-7851 |
Aparece en las colecciones: | (ISQCH) Artículos |
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