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Título: | Carbon-Supported PtRuMo Electrocatalysts for Direct Alcohol Fuel Cells |
Autor: | Martínez Huerta, M. Victoria CSIC ORCID ; Tsiouvaras, Nikolaos CSIC; García, Gonzalo CSIC ORCID; Peña Jiménez, Miguel Antonio CSIC ORCID; Pastor Tejera, Elena; Rodriguez, José L.; García Fierro, José Luis CSIC ORCID | Palabras clave: | Electrocatalysts Direct methanol fuel cells DMFC CO Methanol Ethanol PtRuMo Ternary catalysts |
Fecha de publicación: | 21-oct-2013 | Editor: | Multidisciplinary Digital Publishing Institute | Citación: | Catalysts 3(4): 811-838 (2013) | Resumen: | The review article discusses the current status and recent findings of our investigations on the synthesis and characterization of carbon-supported PtRuMo electrocatalysts for direct alcohol fuel cells. In particular, the effect of the carbon support and the composition on the structure, stability and the activity of the PtRuMo nanoparticles for the electrooxidation of CO, methanol and ethanol have been studied. Different physicochemical techniques have been employed for the analysis of the catalysts structures: X-ray analytical methods (XRD, XPS, TXRF), thermogravimetry (TGA) and transmission electron microscopy (TEM), as well as a number of electrochemical techniques like CO adsorption studies, current-time curves and cyclic voltammetry measurements. Furthermore, spectroscopic methods adapted to the electrochemical systems for in situ studies, such as Fourier transform infrared spectroscopy (FTIRS) and differential electrochemical mass spectrometry (DEMS), have been used to evaluate the oxidation process of CO, methanol and ethanol over the carbon-supported PtRuMo electrocatalysts. | Versión del editor: | https://doi.org/10.3390/catal3040811 | URI: | http://hdl.handle.net/10261/157717 | DOI: | 10.3390/catal3040811 | ISSN: | 2073-4344 |
Aparece en las colecciones: | (ICP) Artículos |
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