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Título: | The microbiological transformation of some ent-kaur-6, 16-dienes by Gibberella fujikuroi |
Autor: | Fraga, Braulio M. CSIC; González, Antonio G.; González, Pedro; Hanson, James R.; Hernández, Melchor G. | Palabras clave: | Gibberella fujikuroi ent-kaur-6, 16-dienes ent-6a, 7a-epoxy-3B, 18-dihydroxykaur-16-3n3 kaurenolide biosynthesis |
Fecha de publicación: | 1983 | Editor: | Elsevier | Citación: | Phytochemistry 22(3): pp. 691-694 (1983) | Resumen: | The preparation of ent-kaur-6, 16-diene and ent-18-hydrosykaur-6, 16-diene from epicandicandiol and of ent-3B, 18-dihydroxykaur-6, 16-diene from foliol is described. On incubation with Gibberella fujikuroi ent-kaur-6, 16-diene gave 7-hydroxykaurenolide and 18-hydroxykaur-6, 16-diene afforded 7, 18-dihydroxykaurenolide, whilst ent-6a,7a-epoxy-3B,18-dihydroxykaur-16-ene was obtained from ent-3B,18-dihydroxykaur-6,16-diene. The possible biosynthetic significance of the 6, 7-epoxidation in kaurenolide formation is noted. | URI: | http://hdl.handle.net/10261/22134 | ISSN: | 0031-9422 |
Aparece en las colecciones: | (IPNA) Artículos |
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PHY-1983-22-691.pdf | 150,19 kB | Adobe PDF | Visualizar/Abrir |
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