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Título:	Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives
Autor:	Vilela, Filipe; Luquin, Asunción CSIC ORCID; Coles, Simon J.; Hursthouse, Michael B.
Palabras clave:	Aldehydes Metal-coordination Rearrangement Sulfur heterocycles Tetrathiafulvalene
Fecha de publicación:	2010
Editor:	Beilstein-Institut zur Förderung der Chemischen Wissenschaften
Citación:	Beilstein Journal of Organic Chemistry 6: 1002-1014 (2010)
Resumen:	We present a series of compounds by exploiting the unusual 1,4-aryl shift observed for electron-rich 1,3-dithiole-2-thione and tetrathiafulvalene (TTF) derivatives in the presence of perchloric acid. The mechanistic features of this rearrangement are discussed since this synthetic strategy provides an alternative route for the synthesis and functionalisation of sulfur rich compounds including redox active compounds of TTFs, and a Ni dithiolene.
Descripción:	13 páginas, 7 figuras, 2 tablas.-- This is an Open Access article under the terms of the Creative Commons Attribution License.-- et al.
Versión del editor:	http://dx.doi.org/10.3762/bjoc.6.113
URI:	http://hdl.handle.net/10261/47860
DOI:	10.3762/bjoc.6.113
ISSN:	1860-5397
Aparece en las colecciones:	(ICMA) Artículos

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Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives