SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation

Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/1003

Título:	SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation
Autor:	Glória, Paulo M. C. Prabhakar, Sundaresan Lobo, Ana M. Gomes, Mário
Palavras-chave:	Química TBDMS
Data:	2003
Editora:	Pergamon
Citação:	Glória PM, Prabhakar S, Lobo AM, Gomes M. SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation. Tetrahedron Lett. 2003;44:8819-21.
Resumo:	Abstract—A new efficient method for deprotection of TBDMS derivatives of phenols, primary alcohols, carboxylic acids and secondary amines, consisting of SbCl5 and MeCN with 0.1% water (w/v), is reported. It effects inter alia desilylation of a CH2OTBDMS group in the presence of a ketal function.
Peer review:	yes
URI:	http://hdl.handle.net/10400.21/1003
ISSN:	0040-4039
Versão do Editor:	http://144.206.159.178/FT/1010/201970/5118247.pdf
Aparece nas colecções:	ESTeSL - Artigos

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SbCl5 wet acetonitrile.pdf		107,44 kB	Adobe PDF	Ver/Abrir