Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10400.21/2745
Título: | A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst |
Autor: | Sutradhar, Manas Kirillova, Marina V. Guedes Da Silva, M. Fátima C. Martins, Luisa Pombeiro, Armando |
Palavras-chave: | Hydrocarbon Oxygenations Vanadium Complexes Crystal-Structure Solid-State Ligand 2-Naphtols Compound Core DFT |
Data: | 5-Nov-2012 |
Editora: | Amer Chemical Soc |
Citação: | SUTRADHAR, Manas; KIRILLOVA, Marina V.; SILVA, M. Fátima C. Guedes da; MARTINS, Luísa M. D. R. S.; POMBEIRO, Armando J. L. - A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst. Inorganic Chemistry. ISSN: 0020-1669. Vol. 51, nr 21, (2012), p. 11229-11231. |
Resumo: | The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions. |
Peer review: | yes |
URI: | http://hdl.handle.net/10400.21/2745 |
ISSN: | 0020-1669 |
Aparece nas colecções: | ISEL - Eng. Quim. Biol. - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst.rep.pdf | 198,44 kB | Adobe PDF | Ver/Abrir |
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