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http://hdl.handle.net/10773/19566
Title: | Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate |
Author: | Yang, Ting-Hai Han, Yin-Feng Shi, Fa-Nian |
Keywords: | LANTHANIDE COORDINATION POLYMERS HYDROTHERMAL SYNTHESIS LUMINESCENCE ACID PR TB EU |
Issue Date: | 2013 |
Publisher: | ASIAN JOURNAL OF CHEMISTRY |
Abstract: | A novel complex, Zn-2(Hpdc)(2)(Ox)(H2O)(4)] (H(2)pdc = pyridine-2,5-dicarboxylic acid, Ox = oxalate), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. Crystal structure analysis reveals that the compound crystallizes in monoclinic space group P2(1)/n, features an interesting 3D-supramolecular network via hydrogen bonding and pi-pi stacking interactions. Cell unit parameter for the compound: a = 10.2152(3) angstrom, b = 9.6535(3) angstrom, c = 10.3594(2) angstrom, beta = 105.664 degrees, V = 983.63(5) angstrom(3), Z = 2, M-r = 623.05, D-c = 2.104 g/cm(3), mu = 2.536 mm(-1), F-(000) = 628, T = 150(2) K, R = 0.0356, wR = 0.0612 for 2510 reflections with I > 2 sigma(I). |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19566 |
DOI: | 10.14233/ajchem.2013.14925 |
ISSN: | 0970-7077 |
Publisher Version: | 10.14233/ajchem.2013.14925 |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Synthesis and crystal structure of 3D-superamolecular zinc complex derived from pyridine-25-dicarboxylate and oxalate_10.14233ajchem.2013.14925.pdf | 1.04 MB | Adobe PDF | View/Open |
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