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http://hdl.handle.net/10773/20790
Title: | Synthesis under high hydrostatic pressure - a new method to prepare 5,10,15,20-tetrakis[4-(substituted amino)-2,3,5,6-tetrafluorophenyl]porphyrins |
Author: | Gomes, Ana T. P. C. Freire, Patricia C. Domingos, Catarina R. M. Neves, Maria G. P. M. S. Cavaleiro, Jose A. S. Almeida Paz, Filipe A. Saraiva, Jorge A. Tome, Augusto C. |
Keywords: | 1,3-DIPOLAR CYCLOADDITION REACTIONS DIELS-ALDER REACTIONS AROMATIC NUCLEOPHILIC SUBSTITUTION BARRELENE-FUSED CHLORINS PORPHYRIN DERIVATIVES MESO-TETRAARYLPORPHYRINS AZOMETHINE YLIDES ORGANIC-SYNTHESIS CATALYSTS BACTERIOCHLORINS |
Issue Date: | 2016 |
Publisher: | WORLD SCI PUBL CO INC |
Abstract: | 5,10,15,20-Tetrakis(pentafluorophenyl) porphyrin reacts with primary alkylamines and heterocyclic amines, at 50 degrees C and under high pressure (450 MPa), to produce the N-substituted tetraamino derivatives in high yields. Under similar conditions, the reaction with the bulky dibutylamine and dipentylamine affords the corresponding mono-substituted dialkylaminoporphyrins in 10% yield. This new protocol arises as a considerable improvement of the methods already known, which usually require high temperatures and are not effective when using secondary amines having long alkyl groups. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20790 |
DOI: | 10.1142/S108842461650111X |
ISSN: | 1088-4246 |
Publisher Version: | 10.1142/S108842461650111X |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Synthesis under high hydrostatic pressure-a new method to prepare 5101520-tetrakis[4-(substituted amino)-2356-tetrafluorophenyl]porphyrins_10.1142S108842461650111X.pdf | 643.99 kB | Adobe PDF |
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