Hybrid Ionic Liquid-Chitosan Membranes for CO2 Separation: Mechanical and Thermal Behavior
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Santos Santamaría, Esther; Rodríguez Fernández, Enrique; Casado Coterillo, Clara; Irabien Gulías, José ÁngelFecha
2016Derechos
© Walter de Gruyter. The final publication is available at www.degruyter.com
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International Journal of Chemical Reactor Engineering.2016 Volume 14, Issue 3, Pages 713–718
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Walter de Gruyter
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Resumen/Abstract
Pure chitosan (CS) and hybrid ionic liquid-chitosan membranes loaded with 5 wt% 1-ethyl-3-methylimidazolium acetate ([emim][Ac]) ionic liquid were prepared in order to improve the thermal behavior of supported ionic liquidmembranes (SILMs) for CO2 separation. Gas permeability, solubility and diffusivity were evaluated in the temperature range 298-323 K. The temperature influence was well described in terms of the Arrhenius-van't Hoff exponential relationships. Activation energies were calculated and comparedwith those obtained for SILMs with the same ionic liquid. The introduction of this ionic liquid in the hybrid solid membrane decreases the permeability activation energy, leading to a lower influence of the temperature in the permeability and diffusivity. Moreover, the thermal behavior is similar to pure chitosan membranes, and the mechanical strength and flexibility were improved due to the introduction of the ionic liquid in the polymer matrix
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