Benefited from the efficiency of hydraulic fracturing and horizon drilling, the production of unconventional oil and gas resources, such as shale gas and tight oil, has grown quickly in 21th century and contributed to the North America oil and gas production. Although the new enhancing oil recover (EOR) technologies and strong demand spike the production of unconventional resources, there are still unknowns in recovery mechanisms and phase behavior in tight rock reservoirs. In such environment, the phase behavior is altered by high capillary pressure owing to the nanoscale pore throats of shale rocks and it may also influence minimum miscibility pressure (MMP), which is an important parameter controlling gas floods for CO2 injection EOR. To investigate this influence, flash calculation is modified with considering capillary pressure and this work implements three different method to calculate MMP: method of characteristics (MOC); multiple mixing cell (MMC); and slim-tube simulation. The results show that CO2 minimum miscibility pressure in nanopore size reservoirs are affected by gas-oil capillary pressure owing to the alternation of key tie lines in displacement. The values of CO2-MMP from three different methods match well.

Moreover, in tight rock reservoirs, the heterogeneous pore size distribution, such as the ones seen in fractured reservoirs, may affect the recovery mechanisms and MMP. This work also investigates the effect of pore size heterogeneity on multicomponent multiphase hydrocarbon fluid composition distribution and its subsequent influence on mass transfer through shale nanopores. According to the simulation results, compositional gradient forms in heterogeneous nanopores of tight reservoirs because oil and gas phase compositions depend on the pore size. Considering that permeability is small in tight rocks and shales, we expect that mass transfer within heterogeneous pore size porous media to be diffusion-dominated. Our results imply that there can be a selective matrix-fracture component mass transfer during both primary production and gas injection secondary recovery in fractured shale rocks. Therefore, molecular diffusion should not be neglected from mass transfer equations for simulations of gas injection EOR or primary recovery of heterogeneous shale reservoirs with pore size distribution.