Total enzymatic resolution of racemic 2-(4-methoxybenzyl)-1-cyclohexanols and 2-(4-methoxybenzyl)-1-cyclopentanols

0194574 - UOCHB-X 20020245 RIV US eng J - Článek v odborném periodiku
Brunet, Ch. - Zarevúcka, Marie - Wimmer, Zdeněk - Legoy, M. D.
Total enzymatic resolution of racemic 2-(4-methoxybenzyl)-1-cyclohexanols and 2-(4-methoxybenzyl)-1-cyclopentanols.
Enzyme and Microbial Technology. Roč. 31, - (2002), s. 609-614. ISSN 0141-0229. E-ISSN 1879-0909
Výzkumný záměr: CEZ:AV0Z4055905
Klíčová slova: enantioselectivity
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 1.773, rok: 2002

Total resolution of the racemic .I.cis./I.- and .I.trans./I.-2-(4-methoxybenzyl)-1-cyclohexanols and 2-(4-methoxybenzyl)-1-cyclopentanols with .I.Candida antarctica./I. lipase B-catalysed transesterification was reached: high temperature (80-100řC) and a_w < 0.1 were a good combination to improve initial rates and to reach maximum (.I.R./I.)-alcohol conversion.
Trvalý link: http://hdl.handle.net/11104/0090249