Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.

0482255 - ÚCHP 2018 CZ eng C - Konferenční příspěvek (zahraniční konf.)
Žádný, Jaroslav - Storch, Jan - Strašák, Tomáš - Církva, Vladimír - Hrbáč, J. - Fekete, Ladislav - Pokorný, Jan - Bulíř, Jiří - Vacek, J.
Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
Book of Abstracts. -, 2017, s. 129. ISBN N.
[Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2017 /52./. Lázně Bělohrad (CZ), 03.11.2017-05.11.2017]
Grant CEP: GA ČR(CZ) GA17-02578S
Institucionální podpora: RVO:67985858 ; RVO:68378271
Klíčová slova: electrosynthesis * helicene * anodic reaction
Obor OECD: Organic chemistry; Physical chemistry (FZU-D)

3-([7]H elicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by cyclic voltammetry with anodic potential limits of +1.5 V or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations; UV-Vis, fluorescence and vibrational spectroscopies, ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics and sensing technologies.
Trvalý link: http://hdl.handle.net/11104/0277637