A new trinuclear Zn(II) complex {[Zn(μ-ONN)(μ.sub.2./sub.-O)(μ-OO)].sub.2./sub.Zn}: Synthesis, characterization, thermal decomposition and antibacterial activity

0482856 - FZÚ 2018 RIV US eng J - Článek v odborném periodiku
Far, B.S. - Grivani, G. - Khalaji, A.D. - Khorshidi, M. - Eigner, Václav - Dušek, Michal
A new trinuclear Zn(II) complex {[Zn(μ-ONN)(μ₂-O)(μ-OO)]₂Zn}: Synthesis, characterization, thermal decomposition and antibacterial activity.
Journal of Cluster Science. Roč. 28, č. 6 (2017), s. 3217-3227. ISSN 1040-7278. E-ISSN 1572-8862
Grant CEP: GA ČR(CZ) GA14-03276S
Institucionální podpora: RVO:68378271
Klíčová slova: trinuclear complex * Schiff base * single-crystal structure analysis * ZnO nano particle * antibacterial activity
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 1.715, rok: 2017

New Trinuclear Zn(II) Complex {[Zn(μ-ONN)(lμ2-O)(μ-OO)]2 has been synthesized by the reaction of a potentially ONN tridentate Schiff base ligand, and N,N-dimethylethylendiamin, with Zn(OAc)2 2H2O in methanol, in the refluxed conditions and characterized by elemental analysis, FTIR and UV–Vis spectroscopy. Single crystal X-ray structure analysis reveals a trinuclear complex with zinc(II) ions connected by three different bridges. The complex is centrosymmetric, with one of the Zn atoms located at the inversion center. The antibacterial activity of ligand and its zinc(II) comp lex were tested against gram-positive and gram-negative bacteria.

Trvalý link: http://hdl.handle.net/11104/0278246