Comment on ´´Dipole-Supported Electronic Resonances Mediate Electron-Induced Amide Bond Cleavage´´

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Fedor, Juraj
Comment on ´´Dipole-Supported Electronic Resonances Mediate Electron-Induced Amide Bond Cleavage´´.
Physical Review Letters. Roč. 124, č. 19 (2020), č. článku 199301. ISSN 0031-9007. E-ISSN 1079-7114
Institucionální podpora: RVO:61388955
Klíčová slova: Electron attachment * Deoxyribonucleic acid * Low-energy electrons
Obor OECD: Physical chemistry
Impakt faktor: 9.161, rok: 2020
Způsob publikování: Omezený přístup

Recently, Lietal.[1]reported cleavage of the amidebond in formamide,N-methylformamide (NMF), andN,N-dimethylformamide (DMF) via dissociative electronattachment (DEA). They concluded that the lowest DEAband is mediated by a novel type of electronic resonance, adipole-supported core-excited resonance. There were twomain arguments for this conclusion: (i) elimination of othercommon types of resonances and (ii) coincidence of theDEA bands with the calculated highly polar excited statesof the neutral. I suggest that one of the mechanisms thatwas eliminated by Lietal., and which is common inorganic molecules, is operative also in the molecules inquestion.
Trvalý link: http://hdl.handle.net/11104/0309305