- Author
- Date
- 18-9-2017
- Title
- Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand
- Journal
- Chemistry-A European Journal
- Volume | Issue number
- 23 | 52
- Pages (from-to)
- 12709-12713
- Number of pages
- 5
- Document type
- Article
- Faculty
- Faculty of Science (FNWI)
- Institute
- Van 't Hoff Institute for Molecular Sciences (HIMS)
- Abstract
-
The tripodal, tetradentate tris(1-(diphenylphosphanyl)-3-methyl-1H-indol-2-yl)phosphane PP3-ligand 1 stabilizes Ru in the RuII, RuI, and Ru0 oxidation states. The octahedral [(PP3)RuII(Cl)2] (2), distorted trigonal bipyramidal [(PP3)RuI(Cl)] (3), and trigonal bipyramidal [(PP3)Ru0(N2)] (4) complexes were isolated and characterized by single-crystal X-ray diffraction, NMR, EPR, IR, and ESI-MS. Both open-shell metalloradical RuI complex 3 and the closed-shell Ru0 complex 4 undergo facile (net) abstraction of a Cl atom from dichloromethane, resulting in formation of the corresponding RuII and RuI complexes 2 and 3, respectively.
- URL
- go to publisher's site
- Language
- English
- Note
- With supplementary file
- Related dataset
- CCDC 1555408: Experimental Crystal Structure Determination
- Related dataset
- CCDC 1555410: Experimental Crystal Structure Determination
- Related dataset
- CCDC 1555409: Experimental Crystal Structure Determination
- Persistent Identifier
- https://hdl.handle.net/11245.1/fa9c5c28-d733-444c-b4ab-435078f702fe
- Downloads
-
Metalloradical(Final published version)
Metalloradical S(Other version)
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