- Author
- Year
- 2011
- Title
- IR spectroscopy on jet-cooled isolated two-station rotaxanes
- Journal
- The Journal of Physical Chemistry. A
- Volume | Issue number
- 115 | 34
- Pages (from-to)
- 9669-9675
- Document type
- Article
- Faculty
- Faculty of Science (FNWI)
- Institute
- Van 't Hoff Institute for Molecular Sciences (HIMS)
- Abstract
-
High-resolution IR spectroscopy has been employed to study isolated, switchable [2]rotaxanes. IR absorption spectra of two-station rotaxanes, their separate thread, and macrocycle components, as well as those of the individual stations incorporated into the thread, have been measured in the 1800-1000 cm-1 region. These spectra have been fully analyzed, aided by quantum chemical predictions of the IR spectra. From these analyses, a comprehensive picture emerges of the conformational structure and binding interactions between the mechanically interlocked components of the rotaxane
- URL
- go to publisher's site
- Language
- English
- Note
- PT: J; SI: SI; TC: 1; UT: WOS:000294146400040
- Persistent Identifier
- https://hdl.handle.net/11245/1.350666
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