- Author
- Year
- 2015
- Title
- Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species
- Journal
- Inorganic Chemistry
- Volume | Issue number
- 54 | 19
- Pages (from-to)
- 9290-9302
- Document type
- Article
- Faculty
- Faculty of Science (FNWI)
- Institute
- Van 't Hoff Institute for Molecular Sciences (HIMS)
- Abstract
-
The redox series [Ir-n(NH(x))(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu(2))(2)) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir-III imido species [Ir(NH) (PNP)] is not stable but undergoes to the respective Ir-II amido and Ir-III nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation.
- URL
- go to publisher's site
- Language
- English
- Note
- With supporting information
- Persistent Identifier
- https://hdl.handle.net/11245/1.500274
- Downloads
- Supplementary materials
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