Near infrared vibrational circular dichroism spectra in the region of 1300 to 800 nm were recorded for 12 enantiomeric pairs of molecules with a home-made dispersive apparatus. With respect to earlier measurements, a better signal-to-noise ratio was obtained, thus allowing a more precise determination of molecular parameters. A detailed examination of the spectra between 1300 and 1100 nm allowed us to correlate the data of the different molecules, based on local properties of given molecular moieties. The relevance of this correlationin configurational and/or conformational studies is discussed.

Vibrational Circular Dichroism in the Near Infrared: instrumental development and applications

LEBON, France;LONGHI, Giovanna;ABBATE, Sergio
2002-01-01

Abstract

Near infrared vibrational circular dichroism spectra in the region of 1300 to 800 nm were recorded for 12 enantiomeric pairs of molecules with a home-made dispersive apparatus. With respect to earlier measurements, a better signal-to-noise ratio was obtained, thus allowing a more precise determination of molecular parameters. A detailed examination of the spectra between 1300 and 1100 nm allowed us to correlate the data of the different molecules, based on local properties of given molecular moieties. The relevance of this correlationin configurational and/or conformational studies is discussed.
File in questo prodotto:
File Dimensione Formato  
Enantiomer-2002.zip

gestori archivio

Tipologia: Full Text
Licenza: DRM non definito
Dimensione 9.05 MB
Formato Unknown
9.05 MB Unknown   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11379/27918
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? 3
  • Scopus 42
  • ???jsp.display-item.citation.isi??? 34
social impact