The C8 and C10 long-range induction coefficients for two like centrosymmetric linear molecules are derived explicitly using the irreducible properties of spherical tensor operators. An application to the H2-H2 system shows that whereas the isotropic induction coefficients are 50-100 times smaller than dispersion, the induction anisotropies γn are always larger than the corresponding dispersion anisotropies.

Long-range induction coefficients for like centrosymmetric linear molecules and an application to H2-H2

MAGNASCO, VALERIO;OTTONELLI, MASSIMO;RUI, MARINA;COSTA, CAMILLA
1998-01-01

Abstract

The C8 and C10 long-range induction coefficients for two like centrosymmetric linear molecules are derived explicitly using the irreducible properties of spherical tensor operators. An application to the H2-H2 system shows that whereas the isotropic induction coefficients are 50-100 times smaller than dispersion, the induction anisotropies γn are always larger than the corresponding dispersion anisotropies.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/245979
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