A shape model for the twisting power of chiral solutes in nematics

The twisting power of chiral probes in nematics is interpreted in terms of a shape model, in which the surface elements of the solute molecules tend to align with the local director. The theoretical treatment is based on a previous approach, suitable for relating order parameters in nematics to molecular shape, and leads to the definition of a molecular pseudo-tensor whose orientational average determines the pitch and handedness of the helical macrostructures. Results of numerical calculations performed for distorted biphenyl and binaphthyl molecules are in agreement with the experimental results.