The title compounds react with C 2N 2 in C 2H 4Cl 2 or CH 2Cl 2 under ambient conditions undergoing cyanation of the organometallic ring. The products are unstable and evolve with different rates to cyanide-containing coordination polymers. [Zn(acac) 2] is a very effective catalyst for the addition of C 2N 2 to Hacac to give 3-(cyanoiminomethyl)pentane-2,4-dione under ambient conditions. © 1983.
The reactivity of cyanogen towards compounds containing active hydrogens at carbon atoms. Part 4. The cyanation of [Mn(acac) 2], [Mn(acac) 3 and [Zn(acac) 2]
BASATO, MARINO;
1983
Abstract
The title compounds react with C 2N 2 in C 2H 4Cl 2 or CH 2Cl 2 under ambient conditions undergoing cyanation of the organometallic ring. The products are unstable and evolve with different rates to cyanide-containing coordination polymers. [Zn(acac) 2] is a very effective catalyst for the addition of C 2N 2 to Hacac to give 3-(cyanoiminomethyl)pentane-2,4-dione under ambient conditions. © 1983.File in questo prodotto:
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