We evaluate the performance of an adhesion buffer layer between ordered metal nanoparticle arrays and dielectric substrates on the particles' morphological manipulation by pulsed laser irradiation. The experiments are performed irradiating with only one nanosecond pulse at 355 nm, triangular nanoprism arrays fabricated by nanosphere lithography (polystyrene spheres with 1030 nm in diameter), followed by film deposition by magnetron sputtering. The reshaping of the nanoprisms into spheres as result of laser-induced melting is investigated for three different materials: prisms made of Cr, Au and Au with a buffer layer made of Cr (Au/Cr). These elements are chosen because their interfacial interaction with the substrates (soda-lime glass and fused silica) is quite different. Our results show that single pulse irradiation at fluences above the metal melting threshold allows the formation of disorder spheres for the case of Au, but ordered spheres for the cases of Cr and Cr/Au. Therefore, the function of the buffer layer is to improve the adhesion between the prisms and the substrate, thus allowing their reshaping by laser-induced melting but preserving their position. The strong interaction between Cr and the substrate is also exploited for the nanostructuration of the substrate by the formation of ordered holes with sub-micrometer dimensions. These findings reboot laser postprocessing of ordered structures fabricated by nanosphere lithography exploit to explore new capacities of nanostructuration.

Buffer-layer-assisted morphological manipulation of metal nanoparticle arrays by laser irradiation

Cesca T.;Balasa I. G.;Reyes-Esqueda J. A.;Mattei G.
2019

Abstract

We evaluate the performance of an adhesion buffer layer between ordered metal nanoparticle arrays and dielectric substrates on the particles' morphological manipulation by pulsed laser irradiation. The experiments are performed irradiating with only one nanosecond pulse at 355 nm, triangular nanoprism arrays fabricated by nanosphere lithography (polystyrene spheres with 1030 nm in diameter), followed by film deposition by magnetron sputtering. The reshaping of the nanoprisms into spheres as result of laser-induced melting is investigated for three different materials: prisms made of Cr, Au and Au with a buffer layer made of Cr (Au/Cr). These elements are chosen because their interfacial interaction with the substrates (soda-lime glass and fused silica) is quite different. Our results show that single pulse irradiation at fluences above the metal melting threshold allows the formation of disorder spheres for the case of Au, but ordered spheres for the cases of Cr and Cr/Au. Therefore, the function of the buffer layer is to improve the adhesion between the prisms and the substrate, thus allowing their reshaping by laser-induced melting but preserving their position. The strong interaction between Cr and the substrate is also exploited for the nanostructuration of the substrate by the formation of ordered holes with sub-micrometer dimensions. These findings reboot laser postprocessing of ordered structures fabricated by nanosphere lithography exploit to explore new capacities of nanostructuration.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3306894
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