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High-field electron spin resonance of spin labels in membranes

MPG-Autoren
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Marsh,  D.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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Kurad,  D.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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Livshits,  V. A.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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Marsh, D., Kurad, D., & Livshits, V. A. (2002). High-field electron spin resonance of spin labels in membranes. Chemistry and Physics of Lipids, 116(1-2 Sp. Iss. SI), 93-114. Retrieved from http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6T2N-45G033H-1-1Y&_cdi=4923&_user=38661&_pii=S0009308402000221&_origin=search&_coverDate=06%2F30%2F2002&_sk=998839998&view=c&wchp=dGLzVtz-zSkzV&md5=c9ca976b47c28ec751a0e56880c5c175&ie=/sdarticle.pdf.


Zitierlink: https://hdl.handle.net/11858/00-001M-0000-0012-F3A7-7
Zusammenfassung
High-field electron spin resonance (ESR) spectroscopy is currently undergoing rapid development. This considerably increases the versatility of spin labelling which, at conventional field strengths, is already well established as a powerful physical technique in membrane biology. Among the unique advantages offered by high-field spectroscopy. particularly for spin-labelled lipids, are sensitivity to non- axial rotation and lateral ordering, a better orientational selection, an extended application to rotational dynamics, and an enhanced sensitivity to environmental polarity. These areas are treated in some depth, along with a detailed consideration of recent developments in the investigation of transmembrane polarity profiles. (C) 2002 Elsevier Science Ireland Ltd. All rights reserved.