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Journal Article

The First Imidazolium-Substituted Metal Alkylidene

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Supplementary Material (public)

om700590v-file002.pdf
(Supplementary material), 6MB

om700590v-file003.cif
(Supplementary material), 36KB

om700590v-file004.cif
(Supplementary material), 36KB

Citation

Occhipinti, G., Bjørsvik, H.-R., Törnroos, K. W., Fürstner, A., & Jensen, V. R. (2007). The First Imidazolium-Substituted Metal Alkylidene. Organometallics, 26(18), 4383-4385. doi:10.1021/om700590v.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0025-7407-E
Abstract
A ruthenium complex coordinated by a bidentate aryloxy-NHC ligand has offered the first example of an imidazolium-substituted metal alkylidene, an analogue of existing phosphonium alkylidenes and metal-substituted ketenes. Investigation of the molecular structure and the quantum chemically obtained electronic structure sheds light on the nature of this new compound and the bonds central to its formation.