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Brønsted Acid Catalyzed Asymmetric Silylation of Alcohols

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Hyodo,  Kengo
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Gandhi,  Shikha
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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van Gemmeren,  Manuel
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Hyodo, K., Gandhi, S., van Gemmeren, M., & List, B. (2015). Brønsted Acid Catalyzed Asymmetric Silylation of Alcohols. Synlett, 26(8), 1093-1095. doi:10.1055/s-0034-1380409.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0026-CE8B-8
Abstract
We report a catalytic enantioselective desymmetrization of meso-1,2-diols by monosilylation using a chiral enantiopure Brønsted acid as catalyst and hexamethyldisilazane (HMDS) as silyl source.