- Author
- Kelly Servaes, Christoph Hennig, Rik Van Deun (UGent) and Christiane Görller-Walrand
- Organization
- Abstract
- The complex formation of uranyl UO22+ with chloride ions in acetonitrile was studied by UV-vis and U L-III EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO2Cl4](2-) species in solution with D-4h symmetry. The distances in the U(VI) coordination sphere are U-O-ax = 1.77 +/- 0.01 angstrom and U-Cl = 2.68 +/- 0.01 angstrom.
- Keywords
- CHLORO COMPLEXES, ELECTRONIC-STRUCTURE, SPECTROSCOPY, SPECTRA, EXAFS, AQUO
Downloads
-
(...).pdf
- full text
- |
- UGent only
- |
- |
- 55.52 KB
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-1190204
- MLA
- Servaes, Kelly, et al. “Structure of [UO2Cl4](2-) in Acetonitrile.” INORGANIC CHEMISTRY, vol. 44, no. 22, 2005, pp. 7705–07, doi:10.1021/ic051098r.
- APA
- Servaes, K., Hennig, C., Van Deun, R., & Görller-Walrand, C. (2005). Structure of [UO2Cl4](2-) in acetonitrile. INORGANIC CHEMISTRY, 44(22), 7705–7707. https://doi.org/10.1021/ic051098r
- Chicago author-date
- Servaes, Kelly, Christoph Hennig, Rik Van Deun, and Christiane Görller-Walrand. 2005. “Structure of [UO2Cl4](2-) in Acetonitrile.” INORGANIC CHEMISTRY 44 (22): 7705–7. https://doi.org/10.1021/ic051098r.
- Chicago author-date (all authors)
- Servaes, Kelly, Christoph Hennig, Rik Van Deun, and Christiane Görller-Walrand. 2005. “Structure of [UO2Cl4](2-) in Acetonitrile.” INORGANIC CHEMISTRY 44 (22): 7705–7707. doi:10.1021/ic051098r.
- Vancouver
- 1.Servaes K, Hennig C, Van Deun R, Görller-Walrand C. Structure of [UO2Cl4](2-) in acetonitrile. INORGANIC CHEMISTRY. 2005;44(22):7705–7.
- IEEE
- [1]K. Servaes, C. Hennig, R. Van Deun, and C. Görller-Walrand, “Structure of [UO2Cl4](2-) in acetonitrile,” INORGANIC CHEMISTRY, vol. 44, no. 22, pp. 7705–7707, 2005.
@article{1190204,
abstract = {{The complex formation of uranyl UO22+ with chloride ions in acetonitrile was studied by UV-vis and U L-III EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO2Cl4](2-) species in solution with D-4h symmetry. The distances in the U(VI) coordination sphere are U-O-ax = 1.77 +/- 0.01 angstrom and U-Cl = 2.68 +/- 0.01 angstrom.}},
author = {{Servaes, Kelly and Hennig, Christoph and Van Deun, Rik and Görller-Walrand, Christiane}},
issn = {{0020-1669}},
journal = {{INORGANIC CHEMISTRY}},
keywords = {{CHLORO COMPLEXES,ELECTRONIC-STRUCTURE,SPECTROSCOPY,SPECTRA,EXAFS,AQUO}},
language = {{eng}},
number = {{22}},
pages = {{7705--7707}},
title = {{Structure of [UO2Cl4](2-) in acetonitrile}},
url = {{http://doi.org/10.1021/ic051098r}},
volume = {{44}},
year = {{2005}},
}
- Altmetric
- View in Altmetric
- Web of Science
- Times cited: