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Pressure assisted osmosis using nanofiltration membranes (PAO-NF) : towards higher efficiency osmotic processes

(2017) JOURNAL OF MEMBRANE SCIENCE. 533. p.250-260
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Abstract
The pressure assisted osmosis (PAO) process has been recently considered as a new strategy to enhance water flux and to limit reverse salt transport (RST), hereby overcoming two critical limitations of forward osmosis (FO) operation through the use of additional pressure on the feed side. With the aim to achieve higher (economically sustainable) fluxes, the use of commercially available nanofiltration (NF) membranes under PAO operating conditions is considered for the first time in this study. When operated under PAO mode, the tested commercial NF membranes clearly outperform the state of the art FO membrane with fluxes up to 36 L m(-2) h(-1) and RST below 0.01 g L-1, demonstrating the relative potential of PAO-NF. For flat sheet NF membrane osmotic contribution was minimal due to intense internal concentration polarisation. However, the tested hollow fiber NF membrane allowed for low internal concentration polarisation and exhibited significant flux even in FO operation. However, transmission of salts from feed to draw solutions (forward salt transport, FST) also occurred and was observed to be linearly proportional with the NF top layer rejection. Therefore, it is an important parameter to consider in the membrane selection in addition to the trade-off between large flux and low RST. The PAO-NF concept also proved to be more efficient in terms of water flux than direct NF operation, owing to a small but significant contribution of osmotic pressure. A modelling study demonstrated that further flux enhancement could be obtained through modification of NF membranes support layer to improve the osmotic contribution. These encouraging initial results warrant the need for a more detailed assessment of the long-term operation and energy requirement of the PAO-NF concept for a range of industrial applications.
Keywords
Pressure assisted osmosis, Nanofiltration, Pre-dilution desalination, Reverse salt diffusion, Forward salt transport, THIN-FILM COMPOSITE, INTERNAL CONCENTRATION POLARIZATION, HOLLOW-FIBER MEMBRANES, DRAW SOLUTE PERMEATION, RETARDED OSMOSIS, POWER-GENERATION, FLUX BEHAVIOR, SUPPORT LAYER, WATER FLUX, DIELECTRIC EXCLUSION

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Citation

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MLA
Blandin, Gaetan, et al. “Pressure Assisted Osmosis Using Nanofiltration Membranes (PAO-NF) : Towards Higher Efficiency Osmotic Processes.” JOURNAL OF MEMBRANE SCIENCE, vol. 533, 2017, pp. 250–60, doi:10.1016/j.memsci.2017.03.048.
APA
Blandin, G., Myat, D. T., Verliefde, A., & Le-Clech, P. (2017). Pressure assisted osmosis using nanofiltration membranes (PAO-NF) : towards higher efficiency osmotic processes. JOURNAL OF MEMBRANE SCIENCE, 533, 250–260. https://doi.org/10.1016/j.memsci.2017.03.048
Chicago author-date
Blandin, Gaetan, Darli T Myat, Arne Verliefde, and Pierre Le-Clech. 2017. “Pressure Assisted Osmosis Using Nanofiltration Membranes (PAO-NF) : Towards Higher Efficiency Osmotic Processes.” JOURNAL OF MEMBRANE SCIENCE 533: 250–60. https://doi.org/10.1016/j.memsci.2017.03.048.
Chicago author-date (all authors)
Blandin, Gaetan, Darli T Myat, Arne Verliefde, and Pierre Le-Clech. 2017. “Pressure Assisted Osmosis Using Nanofiltration Membranes (PAO-NF) : Towards Higher Efficiency Osmotic Processes.” JOURNAL OF MEMBRANE SCIENCE 533: 250–260. doi:10.1016/j.memsci.2017.03.048.
Vancouver
1.
Blandin G, Myat DT, Verliefde A, Le-Clech P. Pressure assisted osmosis using nanofiltration membranes (PAO-NF) : towards higher efficiency osmotic processes. JOURNAL OF MEMBRANE SCIENCE. 2017;533:250–60.
IEEE
[1]
G. Blandin, D. T. Myat, A. Verliefde, and P. Le-Clech, “Pressure assisted osmosis using nanofiltration membranes (PAO-NF) : towards higher efficiency osmotic processes,” JOURNAL OF MEMBRANE SCIENCE, vol. 533, pp. 250–260, 2017.
@article{8566273,
  abstract     = {{The pressure assisted osmosis (PAO) process has been recently considered as a new strategy to enhance water flux and to limit reverse salt transport (RST), hereby overcoming two critical limitations of forward osmosis (FO) operation through the use of additional pressure on the feed side. With the aim to achieve higher (economically sustainable) fluxes, the use of commercially available nanofiltration (NF) membranes under PAO operating conditions is considered for the first time in this study. When operated under PAO mode, the tested commercial NF membranes clearly outperform the state of the art FO membrane with fluxes up to 36 L m(-2) h(-1) and RST below 0.01 g L-1, demonstrating the relative potential of PAO-NF. For flat sheet NF membrane osmotic contribution was minimal due to intense internal concentration polarisation. However, the tested hollow fiber NF membrane allowed for low internal concentration polarisation and exhibited significant flux even in FO operation. However, transmission of salts from feed to draw solutions (forward salt transport, FST) also occurred and was observed to be linearly proportional with the NF top layer rejection. Therefore, it is an important parameter to consider in the membrane selection in addition to the trade-off between large flux and low RST. The PAO-NF concept also proved to be more efficient in terms of water flux than direct NF operation, owing to a small but significant contribution of osmotic pressure. A modelling study demonstrated that further flux enhancement could be obtained through modification of NF membranes support layer to improve the osmotic contribution. These encouraging initial results warrant the need for a more detailed assessment of the long-term operation and energy requirement of the PAO-NF concept for a range of industrial applications.}},
  author       = {{Blandin, Gaetan and Myat, Darli T and Verliefde, Arne and Le-Clech, Pierre}},
  issn         = {{0376-7388}},
  journal      = {{JOURNAL OF MEMBRANE SCIENCE}},
  keywords     = {{Pressure assisted osmosis,Nanofiltration,Pre-dilution desalination,Reverse salt diffusion,Forward salt transport,THIN-FILM COMPOSITE,INTERNAL CONCENTRATION POLARIZATION,HOLLOW-FIBER MEMBRANES,DRAW SOLUTE PERMEATION,RETARDED OSMOSIS,POWER-GENERATION,FLUX BEHAVIOR,SUPPORT LAYER,WATER FLUX,DIELECTRIC EXCLUSION}},
  language     = {{eng}},
  pages        = {{250--260}},
  title        = {{Pressure assisted osmosis using nanofiltration membranes (PAO-NF) : towards higher efficiency osmotic processes}},
  url          = {{http://doi.org/10.1016/j.memsci.2017.03.048}},
  volume       = {{533}},
  year         = {{2017}},
}

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