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http://hdl.handle.net/1942/18675| Title: | Quinoxaline-Based Cyclo(oligophenylenes) | Authors: | MARIN, Lidia KUDRJASOVA, Julija VERSTAPPEN, Pieter PENXTEN, Huguette Robeyns, Koen LUTSEN, Laurence VANDERZANDE, Dirk MAES, Wouter |
Issue Date: | 2015 | Publisher: | AMER CHEMICAL SOC | Source: | JOURNAL OF ORGANIC CHEMISTRY, 80 (4), p. 2425-2430 | Abstract: | A series of fully conjugated quinoxaline-based oligophenylene macrocycles is synthesized by Ni-0-mediated Yamamoto-type diaryl homocoupling of (fluorinated) 2,3-bis(4'-bromophenyl)quinoxaline precursors. Cyclotrimers and cyclotetramers are obtained as the dominant reaction products. The cyclooligomers are fully characterized, including single-crystal X-ray structures, and their optoelectronic properties are analyzed with respect to possible applications in hostguest chemistry and organic electronics. | Notes: | [Marin, Lidia; Kudrjasova, Julija; Verstappen, Pieter; Penxten, Huguette; Lutsen, Laurence; Vanderzande, Dirk J. M.; Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. [Marin, Lidia; Kudrjasova, Julija; Verstappen, Pieter; Penxten, Huguette; Lutsen, Laurence; Vanderzande, Dirk J. M.; Maes, Wouter] IMEC, IMOMEC Ass Lab, B-3590 Diepenbeek, Belgium. [Robeyns, Koen] UCL, IMCN, B-1348 Louvain La Neuve, Belgium. | Document URI: | http://hdl.handle.net/1942/18675 | ISSN: | 0022-3263 | e-ISSN: | 1520-6904 | DOI: | 10.1021/jo502771a | ISI #: | 000349943000041 | Rights: | © 2015 American Chemical Society. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2016 |
| Appears in Collections: | Research publications |
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| jo502771a.pdf Restricted Access | 1.14 MB | Adobe PDF | View/Open Request a copy |
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