The preferred conformations in solution of five dolabellane diterpenes [4-8] previously isolated from marine organisms have been determined on the basis of a complete H-1- and C-13-nmr analysis, including NOESY and lanthanide-induced shift experiments, in combination with MM2 calculations. This study led also to a revision of the stereochemistry for three of these dolabellanes.
STEREOCHEMISTRY AND CONFORMATION OF DOLABELLANE DITERPENES - AN NMR AND MOLECULAR MECHANICS STUDY
TRINGALI, Corrado;
1995-01-01
Abstract
The preferred conformations in solution of five dolabellane diterpenes [4-8] previously isolated from marine organisms have been determined on the basis of a complete H-1- and C-13-nmr analysis, including NOESY and lanthanide-induced shift experiments, in combination with MM2 calculations. This study led also to a revision of the stereochemistry for three of these dolabellanes.File in questo prodotto:
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