Artículo

Landa, R.A.; Jorge, G.A.; Molina, F.V.; Antonel, P.S. "Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles" (2013) IEEE Transactions on Magnetics. 49(8):4602-4605
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

In this work, a facile synthesis of Fe3O4/Ag nanoparticles, with magnetic properties and electrical conductivity, was successfully developed, by reducing Ag(I) ions with D-Glucose, in the presence of a dispersion of superparamagnetic Fe3O4 nanoparticles, under ultrasound treatment. Poly(vinylpyrrolidone) (PVP) was used as protecting agent and Ag(I) were incorporated in different molar ratios with respect to Fe3O4 nanoparticles. The obtained particles were characterized by XRD studies, SEM and TEM observation, Energy Dispersive X-Ray Spectroscopy (EDS), DC magnetization and conductivity measurements. From TEM and SEM observation it was found that the PVP protection has shown to be partial, as the Fe3O4 nanoparticles have a lower diameter after the reduction treatment. Despite this, the particles retain the superparamagnetic behavior and the saturation magnetization decreases as the Ag content increases. From conductivity measurements, a minimum Ag(I)/Fe3O4 molar ratio = 1.75 was needed in order to observe electrical conductivity in the metallic regime. © 1965-2012 IEEE.

Registro:

Documento: Artículo
Título:Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles
Autor:Landa, R.A.; Jorge, G.A.; Molina, F.V.; Antonel, P.S.
Filiación:Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires C1428EGA, Argentina
Instituto de Ciencias, Universidad Nacional de General Sarmiento, Los Polvorines, Buenos Aires 1633, Argentina
Palabras clave:Conducting materials; Magnetic nanoparticles; Magnetite; Silver; Conducting materials; Conductivity measurements; Electrical conductivity; Energy dispersive X ray spectroscopy; Magnetic nano-particles; Polyvinyl pyrrolidone; Superparamagnetic behavior; Ultrasound treatments; Electric conductivity; Electric conductivity measurement; Magnetite; Nanoparticles; Saturation magnetization; Superparamagnetism; X ray spectroscopy; Silver
Año:2013
Volumen:49
Número:8
Página de inicio:4602
Página de fin:4605
DOI: http://dx.doi.org/10.1109/TMAG.2013.2255588
Título revista:IEEE Transactions on Magnetics
Título revista abreviado:IEEE Trans Magn
ISSN:00189464
CODEN:IEMGA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00189464_v49_n8_p4602_Landa

Referencias:

  • Kimishima, Y., Yamada, W., Uehara, M., Asaka, T., Kimoto, K., Matsui, Y., Study on anomalous magnetoresistance in nano-Fe3O 4/Ag granular system (2007) Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 138 (1), pp. 69-73. , DOI 10.1016/j.mseb.2007.01.019, PII S0921510707000281
  • Chudasama, B., Vala, A.K., Andhariya, N., Upadhyay, R.V., Mehta, R.V., Antifungal activity of multifunctional Fe O -Ag nanocolloids (2011) J. Mag. Mag. Mat., 232, pp. 1233-1237
  • Babes, L., Denizot, B., Tanguy, G., Le Jeune, J.J., Jallet, P., Synthesis of iron oxide nanoparticles used as MRI contrast agents: A parametric study (1999) Journal of Colloid and Interface Science, 212 (2), pp. 474-482. , DOI 10.1006/jcis.1998.6053
  • Kubovcáková, M., Koneracká, M., Závisová, V., Múcková, M., Timko, M., Schmidtová, L., Bartos, P., Kopcansky, P., Biodistribution and in vivo anticancer effects of taxol loaded magnetic nanospheres (2013) IEEE Trans. Magn., 49 (1), pp. 353-358
  • Wang, J., Sun, Y., Wang, L.Y., Zhu, X.N., Zhang, H.Q., Song, D.Q., Surface plasmon resonance biosensor based on Fe O /Au nanocomposites (2010) Colloids Surf. B: Biointerfaces, 81, pp. 600-606
  • Pollert, E., Kaspar, P., Záveta, K., Herynek, V., Burian, M., Jerdelová, P., Magnetic nanoparticles for therapy and diagnosis (2013) IEEE Trans. Magn., 49 (1), pp. 7-10
  • Garza-Navarro, M., Torres-Castro, A., González, V., Ortiz, U., De La Rosa, E., Magnetite and magnetite/silver core/shell nanoparticles with diluted magnetic-like behavior (2010) J. Solid. State Chem., 183, pp. 99-104
  • Shin, K.S., Choi, J.-Y., Parkh. J Jang, C.S., Kim, K., Facile synthesis and catalytic application of silver-deposited magnetic nanoparticles (2009) Catal. Lett., 133, pp. 1-7
  • Iglesias-Silva, E., Rivas, J., Leén Isidro, L.M., Lépez-Quintela, M.A., Synthesis of silver-coatedmagnetic nanoparticles (2007) J. Non-Cryst. Solids, 353, pp. 829-831
  • Chi, Y., Yuan, Q., Li, Y., Tu, J., Zhao, L., Li, N., Li, X., Synthesis of Fe O @SiO -Ag magnetic nanocomposite based on small-sized and highly dispersed silver nanoparticles for catalytic reduction of 4-nitrophenol (2012) J. Colloid. Interf. Sci., 383, pp. 96-102
  • Zhang, Z., Jiang, W., Gong, X., Zhang, Z., Sonochemical synthesis and characterization of magnetic separable Fe O /Ag composites and its catalytic properties (2010) J. Alloys Comp., 508, pp. 400-405
  • Sun, Y., Tian, Y., He, M., Zhao, Q., Chen, C., Hu, C., Liu, Y., Controlled synthesis of Fe O /Ag core-shell composite nanoparticles with high electrical conductivity (2012) J. Electron. Mater., 41, pp. 519-523
  • Kim, Y.I., Kim, D., Lee, C.S., Synthesis and characterization of CoFe O magnetic nanoparticles prepared by temperature-controlled comprecipitation method (2003) Physica B: Cond. Matter, 337, pp. 42-51
  • Antonel, P.S., Jorge, G., Perez, O.E., Butera, A., Leyva, A.G., Negri, R.M., Magnetic and elastic properties of CoFe O -polydimethylsiloxane magnetically oriented elastomer nanocomposites (2011) J. Appl. Phys., 110 (8), p. 043920
  • Mietta, J.L., Ruiz, M.M., Antonel, P.S., Perez, O.E., Buterag, J.A., Negri, R.M., Anisotropic magnetoresistance and piezoresistivity in structured Fe O -silver particles in PDMS elastomers at room temperature (2012) Langmuir, 28, pp. 6985-6996
  • Vasileva, P., Donkova, B., Karadjova, I., Dushkin, C., Synthesis of starch-stabilized silver nanoparticles and their application as a surface plasmon resonance-based sensor of hydrogen peroxide (2011) Colloids and Surfaces A: Physicochem. Eng. Aspects, 382, pp. 203-210
  • Rasband, W., (2012) Proc. Image J., , Bethesda, MD, Nat. Inst. Health, Res. Services Branch
  • Angermann, A., Töpfer, J., Synthesis of magnetite nanoparticles by thermal decomposition of ferrous oxalate dihydrate (2008) J. Mater. Sci., 43, pp. 5123-5130
  • Han, D.H., Wang, J.P., Luo, H.L., Crystallite size effect on saturation magnetization of fine ferromagnetic particles (1994) J. Mag. Mag. Mater., 136, pp. 176-182
  • Lu, H.M., Zheng, W.T., Jiang, Q., Saturation magnetization of ferromagnetic and ferrimagnetic nanocrystals at room temperature (2007) Journal of Physics D: Applied Physics, 40 (2), pp. 320-325. , DOI 10.1088/0022-3727/40/2/006, PII S0022372707351917, 006
  • Hsu, Y.-C., Chung, D.D.L., Silver particle carbon-matrix composites as thick films for electrical applications (2007) Journal of Electronic Materials, 36 (9), pp. 1188-1192. , DOI 10.1007/s11664-007-0187-4

Citas:

---------- APA ----------
Landa, R.A., Jorge, G.A., Molina, F.V. & Antonel, P.S. (2013) . Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles. IEEE Transactions on Magnetics, 49(8), 4602-4605.
http://dx.doi.org/10.1109/TMAG.2013.2255588
---------- CHICAGO ----------
Landa, R.A., Jorge, G.A., Molina, F.V., Antonel, P.S. "Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles" . IEEE Transactions on Magnetics 49, no. 8 (2013) : 4602-4605.
http://dx.doi.org/10.1109/TMAG.2013.2255588
---------- MLA ----------
Landa, R.A., Jorge, G.A., Molina, F.V., Antonel, P.S. "Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles" . IEEE Transactions on Magnetics, vol. 49, no. 8, 2013, pp. 4602-4605.
http://dx.doi.org/10.1109/TMAG.2013.2255588
---------- VANCOUVER ----------
Landa, R.A., Jorge, G.A., Molina, F.V., Antonel, P.S. Synthesis and properties of bifunctional Fe3O4/Ag nanoparticles. IEEE Trans Magn. 2013;49(8):4602-4605.
http://dx.doi.org/10.1109/TMAG.2013.2255588