Abstract:
Delamination and restacking of dodecyl-sulfate-intercalated hydrotalcite in CCl4 and toluene were followed by in situ low-angle XRD. It is shown that exfoliation of hybrid layered double hydroxides must be rationalized in terms of the miscibility of the solvent and the aliphatic chains of the intercalated amphiphilic anions. The macroscopic appearance of diluted systems, however, is determined by the interaction between the edges of the exfoliated lamella. © 2004 Elsevier Inc. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
Autor: | Jobbágy, M.; Regazzoni, A.E. |
Filiación: | INQUIMAE, Fac. de Ciencias Exactas Y Naturales, Ciudad Universitaria, 1428 Buenos Aires, Argentina Unidad de Actividad Química, Centro Atómico Constituyentes, Comn. Nac. de Ener. Atómica, Av. General Paz 1499, 1650 San Martín, Argentina Inst. de Tecn. Jorge Sabato, Univ. Nac. de Gen. San Martín, Av. General Paz 1499, 1650 San Martín, Argentina
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Palabras clave: | Delamination; In situ processing; Solubility; Solvents; X ray diffraction; Double hydroxides; Exfoliation; Hydrotalcites; Restacking; Carbon tetrachloride; aliphatic compound; amphophile; anion; chloride; dodecyl sulfate; hydrotalcite; hydroxide; solvent; toluene; article; dilution; hybrid; intercalation complex; miscibility; priority journal; X ray diffraction |
Año: | 2004
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Volumen: | 275
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Número: | 1
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Página de inicio: | 345
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Página de fin: | 348
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DOI: |
http://dx.doi.org/10.1016/j.jcis.2004.01.082 |
Título revista: | Journal of Colloid and Interface Science
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Título revista abreviado: | J. Colloid Interface Sci.
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ISSN: | 00219797
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CODEN: | JCISA
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CAS: | chloride, 16887-00-6; dodecyl sulfate, 151-41-7; hydrotalcite, 12304-65-3; hydroxide, 14280-30-9; toluene, 108-88-3
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219797_v275_n1_p345_Jobbagy |
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Citas:
---------- APA ----------
Jobbágy, M. & Regazzoni, A.E.
(2004)
. Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD. Journal of Colloid and Interface Science, 275(1), 345-348.
http://dx.doi.org/10.1016/j.jcis.2004.01.082---------- CHICAGO ----------
Jobbágy, M., Regazzoni, A.E.
"Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD"
. Journal of Colloid and Interface Science 275, no. 1
(2004) : 345-348.
http://dx.doi.org/10.1016/j.jcis.2004.01.082---------- MLA ----------
Jobbágy, M., Regazzoni, A.E.
"Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD"
. Journal of Colloid and Interface Science, vol. 275, no. 1, 2004, pp. 345-348.
http://dx.doi.org/10.1016/j.jcis.2004.01.082---------- VANCOUVER ----------
Jobbágy, M., Regazzoni, A.E. Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD. J. Colloid Interface Sci. 2004;275(1):345-348.
http://dx.doi.org/10.1016/j.jcis.2004.01.082