Artículo

Krivdin, L.B.; Zinchenko, S.V.; Shcherbakov, V.V.; Kalabin, G.A.; Contreras, R.H.; Tufro, M.F.; Ruiz de Azua, M.C.; Giribet, C.G. "Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime" (1989) Journal of Magnetic Resonance (1969). 84(1):1-8
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Abstract:

The difference between 1Jcc(Z) and 1Jcc (E) for acetoxime is experimentally and theoretically studied as a nitrogen lone-pair orientational effect. Experimentally, it is observed that this difference almost disappears upon full protonation. Theoretically, the most recent version of the IPPP program is used, finding that the N lone pair contributes to the couplings a positive component for 1Jcc(Z) and a negative one for 1Jcc(E), which are found to be the main cause of this difference. © 1989.

Registro:

Documento: Artículo
Título:Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime
Autor:Krivdin, L.B.; Zinchenko, S.V.; Shcherbakov, V.V.; Kalabin, G.A.; Contreras, R.H.; Tufro, M.F.; Ruiz de Azua, M.C.; Giribet, C.G.
Filiación:Department of Chemistry, University ofirkutsk, Irkutsk, 664003, Russian Federation
Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. 1, 1428 Buenos Aires, Argentina
Año:1989
Volumen:84
Número:1
Página de inicio:1
Página de fin:8
DOI: http://dx.doi.org/10.1016/0022-2364(89)90002-4
Título revista:Journal of Magnetic Resonance (1969)
ISSN:00222364
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222364_v84_n1_p1_Krivdin

Referencias:

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Citas:

---------- APA ----------
Krivdin, L.B., Zinchenko, S.V., Shcherbakov, V.V., Kalabin, G.A., Contreras, R.H., Tufro, M.F., Ruiz de Azua, M.C.,..., Giribet, C.G. (1989) . Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime. Journal of Magnetic Resonance (1969), 84(1), 1-8.
http://dx.doi.org/10.1016/0022-2364(89)90002-4
---------- CHICAGO ----------
Krivdin, L.B., Zinchenko, S.V., Shcherbakov, V.V., Kalabin, G.A., Contreras, R.H., Tufro, M.F., et al. "Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime" . Journal of Magnetic Resonance (1969) 84, no. 1 (1989) : 1-8.
http://dx.doi.org/10.1016/0022-2364(89)90002-4
---------- MLA ----------
Krivdin, L.B., Zinchenko, S.V., Shcherbakov, V.V., Kalabin, G.A., Contreras, R.H., Tufro, M.F., et al. "Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime" . Journal of Magnetic Resonance (1969), vol. 84, no. 1, 1989, pp. 1-8.
http://dx.doi.org/10.1016/0022-2364(89)90002-4
---------- VANCOUVER ----------
Krivdin, L.B., Zinchenko, S.V., Shcherbakov, V.V., Kalabin, G.A., Contreras, R.H., Tufro, M.F., et al. Theoretical and experimental study of the orientational nitrogen lone-pair effect on 1J(13C13C) couplings in acetoxime. 1989;84(1):1-8.
http://dx.doi.org/10.1016/0022-2364(89)90002-4