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Abstract:

1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved.

Registro:

Documento: Artículo
Título:The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
Autor:Deulofeu, V.; Deferrari, J.O.
Filiación:Laboratorio de Química Orgánica, Facultad de Ciencias Exactas, Físicas y Naturales, Laboratorio de Química Biológica, Facultad de Ciencias Médicas, Buenos Aires, Argentina
Año:1952
Volumen:17
Número:8
Página de inicio:1087
Página de fin:1092
DOI: http://dx.doi.org/10.1021/jo50008a003
Título revista:Journal of Organic Chemistry
Título revista abreviado:J. Org. Chem.
ISSN:00223263
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v17_n8_p1087_Deulofeu

Citas:

---------- APA ----------
Deulofeu, V. & Deferrari, J.O. (1952) . The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation. Journal of Organic Chemistry, 17(8), 1087-1092.
http://dx.doi.org/10.1021/jo50008a003
---------- CHICAGO ----------
Deulofeu, V., Deferrari, J.O. "The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation" . Journal of Organic Chemistry 17, no. 8 (1952) : 1087-1092.
http://dx.doi.org/10.1021/jo50008a003
---------- MLA ----------
Deulofeu, V., Deferrari, J.O. "The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation" . Journal of Organic Chemistry, vol. 17, no. 8, 1952, pp. 1087-1092.
http://dx.doi.org/10.1021/jo50008a003
---------- VANCOUVER ----------
Deulofeu, V., Deferrari, J.O. The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation. J. Org. Chem. 1952;17(8):1087-1092.
http://dx.doi.org/10.1021/jo50008a003