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Abstract:

Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediates in the production of I, II and III. The basic sequences followed in the formation of those and of other minor products are outlined in the Scheme. Reaction conditions can be adjusted to obtain III in a high yield or to prevent further reaction of the first intermediate and obtain diarylalkylcarbinols, or substituted tetrahydrofurans. © 1983.

Registro:

Documento: Artículo
Título:The reaction of phenyllithium with carbon monoxide
Autor:Nudelman, N.S.; Vatale, A.A.
Filiación:Depto. de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciuda Universitaria, Pab. II, P. 3, 1428 Buenos Aires, Argentina
Año:1983
Volumen:241
Número:2
Página de inicio:143
Página de fin:156
DOI: http://dx.doi.org/10.1016/S0022-328X(00)98502-4
Título revista:Journal of Organometallic Chemistry
Título revista abreviado:J. Organomet. Chem.
ISSN:0022328X
CODEN:JORCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022328X_v241_n2_p143_Nudelman

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Citas:

---------- APA ----------
Nudelman, N.S. & Vatale, A.A. (1983) . The reaction of phenyllithium with carbon monoxide. Journal of Organometallic Chemistry, 241(2), 143-156.
http://dx.doi.org/10.1016/S0022-328X(00)98502-4
---------- CHICAGO ----------
Nudelman, N.S., Vatale, A.A. "The reaction of phenyllithium with carbon monoxide" . Journal of Organometallic Chemistry 241, no. 2 (1983) : 143-156.
http://dx.doi.org/10.1016/S0022-328X(00)98502-4
---------- MLA ----------
Nudelman, N.S., Vatale, A.A. "The reaction of phenyllithium with carbon monoxide" . Journal of Organometallic Chemistry, vol. 241, no. 2, 1983, pp. 143-156.
http://dx.doi.org/10.1016/S0022-328X(00)98502-4
---------- VANCOUVER ----------
Nudelman, N.S., Vatale, A.A. The reaction of phenyllithium with carbon monoxide. J. Organomet. Chem. 1983;241(2):143-156.
http://dx.doi.org/10.1016/S0022-328X(00)98502-4