Artículo
Santori, G.F.; Casella, M.L.; Siri, G.J.; Ferretti, O.A.; Moglioni, A.; Iglesias, G.M. "Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4" (2000) Studies in Surface Science and Catalysis. 130 C:2063-2068
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Abstract:
Silica supported bimetallic and organobimetallic PtSn catalysts were prepared by Surface Organometallic Chemistry on Metals and tested in the hydrogenation of different carbonylic compounds (butanal, butanone, cyclohexanone, benzaldehyde, crotonaldehyde and cinnamaldehyde). It was studied the influence of the Sn/Pt atomic ratio on the hydrogenation of cinnamaldehyde, having been found an optimum of approximately 0.4. The selective hydrogenation of C=O group in polyfunctional molecules can be explained on the basis of the combination of geometric (specially in organobimetallic catalysts), and electronic effects due to the presence of ionic tin. © 2000 Elsevier Science B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4 |
| Autor: | Santori, G.F.; Casella, M.L.; Siri, G.J.; Ferretti, O.A.; Moglioni, A.; Iglesias, G.M. |
| Filiación: | CINDECA (UNLP-CONICET), 47 No 257, (1900) La Plata, Argentina Facultad de Ingeniería, UNLP, 47 No 257, (1900) La Plata, Argentina Departamento de Química Orgánica, UBA, Junín 954, (1113) Buenos Aires, Argentina |
| Palabras clave: | 2 butanone; benzaldehyde; butyraldehyde; carbonyl derivative; cinnamaldehyde; crotonaldehyde; cyclohexanone; metal; organometallic compound; platinum; silicon dioxide; tin derivative; catalysis; catalyst; chemical reaction; conference paper; gas chromatography; hydrogenation; reaction analysis; temperature |
| Año: | 2000 |
| Volumen: | 130 C |
| Página de inicio: | 2063 |
| Página de fin: | 2068 |
| Título revista: | Studies in Surface Science and Catalysis |
| Título revista abreviado: | Stud. Surf. Sci. Catal. |
| ISSN: | 01672991 |
| CODEN: | SSCTD |
| CAS: | 2 butanone, 78-93-3; benzaldehyde, 100-52-7; butyraldehyde, 123-72-8; cinnamaldehyde, 104-55-2; crotonaldehyde, 4170-30-3; cyclohexanone, 108-94-1; platinum, 7440-06-4; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v130C_n_p2063_Santori |
Referencias:
- Ponec, V., (1997) Appl. Catal. A: Gen., 149, p. 27
- Poltarzewski, Z., Galvagno, S., Pietropaolo, R., Staiti, P., (1986) J. Catal., 102, p. 190
- Margitfalvi, J., Hegedüs, M., Göbölös, S., Kern-Tálas, E., Szedlacsek, P., Szabó, S., Nagy, S., (1984) Proc.8th Int. Congr. on Catal., 4, p. 903. , Berlin, Verlag-Chemie
- Ferretti, O.A., Bettega De Pauli, L., Candy, J.P., Mabilon, G., Bournonville, J.P., (1987) Stud. Surf. Sci. Catal., 31, p. 713
- Didillon, B., Candy, J.P., Lepeltier, F., Ferretti, O.A., Basset, J.M., (1993) Stud. Surf. Sci. Catal., 78, p. 205
- Santori, G., Casella, M., Siri, G., Ferretti, O., (1998) Proc. XVI Simp. Iberoam. Catal., 2, p. 597. , A. Centeno et al. Eds
- Santori, G., Casella, M., Siri, G., Aduriz, H., Ferretti, O., Appl. Catal. A: Gen., , in press
- Gallezot, P., Giroir-Fendler, A., Richard, D., (1990) Catal. Lett., 5, p. 169
Citas:
---------- APA ----------
Santori, G.F., Casella, M.L., Siri, G.J., Ferretti, O.A., Moglioni, A. & Iglesias, G.M. (2000) . Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4. Studies in Surface Science and Catalysis, 130 C, 2063-2068.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v130C_n_p2063_Santori [ ]
---------- CHICAGO ----------
Santori, G.F., Casella, M.L., Siri, G.J., Ferretti, O.A., Moglioni, A., Iglesias, G.M. "Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4" . Studies in Surface Science and Catalysis 130 C (2000) : 2063-2068.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v130C_n_p2063_Santori [ ]
---------- MLA ----------
Santori, G.F., Casella, M.L., Siri, G.J., Ferretti, O.A., Moglioni, A., Iglesias, G.M. "Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4" . Studies in Surface Science and Catalysis, vol. 130 C, 2000, pp. 2063-2068.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v130C_n_p2063_Santori [ ]
---------- VANCOUVER ----------
Santori, G.F., Casella, M.L., Siri, G.J., Ferretti, O.A., Moglioni, A., Iglesias, G.M. Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4. Stud. Surf. Sci. Catal. 2000;130 C:2063-2068.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v130C_n_p2063_Santori [ ]
