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Abstract:

Silica nanoparticles were surface-functionalized with diazonium groups. The reaction steps leading to the formation of the diazonium functionality were followed with IR and XPS, and the structure of the diazonium-functionalized nanoparticle was confirmed with solid state NMR. Nanoparticle size distribution was determined with DLS, SEM, and TEM. The nanoparticles were then covalently bonded to gold and iron surfaces. Their spatial distribution over the metal surface was analyzed by SEM. Diazonium modification of nanoparticles represents a new method for the covalent attachment of nanoparticles to metal surfaces. © 2008 American Chemical Society.

Registro:

Documento: Artículo
Título:Synthesis and characterization of diazonium functionalized nanoparticles for deposition on metal surfaces
Autor:Joselevich, M.; Williams, F.J.
Filiación:Departamento de Química de Superficies y Recubrimientos, Tenaris, Simini 250, B2804MHA, Campana, Buenos Aires, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina
Palabras clave:Gold deposits; Nanoparticles; Nanostructured materials; Nuclear magnetic resonance; Secondary emission; Silica; Size distribution; Covalent attachments; Covalently bonded; Functionalized; Functionalized nanoparticles; Iron surfaces; Metal surfaces; Nanoparticle size distributions; Reaction steps; Silica nanoparticles; Solid state nmr; Spatial distributions; Synthesis and characterizations; Nanostructures
Año:2008
Volumen:24
Número:20
Página de inicio:11711
Página de fin:11717
DOI: http://dx.doi.org/10.1021/la802247k
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v24_n20_p11711_Joselevich

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Citas:

---------- APA ----------
Joselevich, M. & Williams, F.J. (2008) . Synthesis and characterization of diazonium functionalized nanoparticles for deposition on metal surfaces. Langmuir, 24(20), 11711-11717.
http://dx.doi.org/10.1021/la802247k
---------- CHICAGO ----------
Joselevich, M., Williams, F.J. "Synthesis and characterization of diazonium functionalized nanoparticles for deposition on metal surfaces" . Langmuir 24, no. 20 (2008) : 11711-11717.
http://dx.doi.org/10.1021/la802247k
---------- MLA ----------
Joselevich, M., Williams, F.J. "Synthesis and characterization of diazonium functionalized nanoparticles for deposition on metal surfaces" . Langmuir, vol. 24, no. 20, 2008, pp. 11711-11717.
http://dx.doi.org/10.1021/la802247k
---------- VANCOUVER ----------
Joselevich, M., Williams, F.J. Synthesis and characterization of diazonium functionalized nanoparticles for deposition on metal surfaces. Langmuir. 2008;24(20):11711-11717.
http://dx.doi.org/10.1021/la802247k