Artículo
Ayude, M.A.; Cassanello, M.C.; Haure, P.M.; Martínez, O.M. "Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale" (2005) Industrial and Engineering Chemistry Research. 44(25):9594-9600
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Abstract:
The behavior of an isothermal catalytic particle in a TBR with ON-OFF liquid flow modulation has been modeled considering isothermal conditions. The impact of catalytic properties has been investigated considering uniform and egg shell distributions. Furthermore, the effect of varying inert core porosity for egg shell catalysts has also been addressed. The model represents experimental trends observed for slow and intermediate cycling. In most cases, egg shell catalysts presented a better performance in comparison with uniform catalysts. However, during cycling, performance depends on working conditions and catalytic properties. Therefore, catalyst design and mode of operation are related issues that need to be defined jointly. The relevance of internal processes (reaction, diffusion, and accumulation) and external transport on overall performance has been addressed. Therefore, the model would serve as a basis, coupled with the development at reactor scale, for the integral reactor design. © 2005 American Chemical Society.
Registro:
| Documento: | Artículo |
| Título: | Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale |
| Autor: | Ayude, M.A.; Cassanello, M.C.; Haure, P.M.; Martínez, O.M. |
| Filiación: | INTEMA, CONICET, UNMdP, J.B. Justo 4302, 7600 Mar del Plata, Argentina PINMATE, Dep. Industrias, FCEyN-UBA Int., Güiraldes 2620, C1428BGA Buenos Aires, Argentina Dep. Ing. Química, FI-UNLP-CINDECA, Calls 47 No. 257, 1900 La Plata, Argentina |
| Palabras clave: | Catalysts; Industrial engineering; Mathematical models; Porosity; Catalyst design; Egg shell distributions; Liquid flow modulation; Trickle bed reactors; Chemical reactors; catalyst; design; trickle bed reactor |
| Año: | 2005 |
| Volumen: | 44 |
| Número: | 25 |
| Página de inicio: | 9594 |
| Página de fin: | 9600 |
| DOI: | http://dx.doi.org/10.1021/ie0502741 |
| Título revista: | Industrial and Engineering Chemistry Research |
| Título revista abreviado: | Ind. Eng. Chem. Res. |
| ISSN: | 08885885 |
| CODEN: | IECRE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v44_n25_p9594_Ayude |
Referencias:
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Citas:
---------- APA ----------
Ayude, M.A., Cassanello, M.C., Haure, P.M. & Martínez, O.M. (2005) . Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale. Industrial and Engineering Chemistry Research, 44(25), 9594-9600.http://dx.doi.org/10.1021/ie0502741
---------- CHICAGO ----------
Ayude, M.A., Cassanello, M.C., Haure, P.M., Martínez, O.M. "Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale" . Industrial and Engineering Chemistry Research 44, no. 25 (2005) : 9594-9600.http://dx.doi.org/10.1021/ie0502741
---------- MLA ----------
Ayude, M.A., Cassanello, M.C., Haure, P.M., Martínez, O.M. "Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale" . Industrial and Engineering Chemistry Research, vol. 44, no. 25, 2005, pp. 9594-9600.http://dx.doi.org/10.1021/ie0502741
---------- VANCOUVER ----------
Ayude, M.A., Cassanello, M.C., Haure, P.M., Martínez, O.M. Periodic operation of trickle bed reactors: An approach to catalyst design through modeling at the particle scale. Ind. Eng. Chem. Res. 2005;44(25):9594-9600.http://dx.doi.org/10.1021/ie0502741
