Artículo

Natkaeo, A.; Phokharatkul, D.; Hodak, J.H.; Wisitsoraat, A.; Hodak, S.K. "Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films" (2018) Sensors and Actuators, B: Chemical. 260:571-580
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Abstract:

The detection of the toxic H2S gas is of great practical, environmental and industrial interest. This work presents sensing devices fabricated with Ag-doped CaCu3Ti4O12 (CCTO) thin films using a cost effective sol-gel deposition method. When compared with undoped CCTO sensors, very low doping levels of Ag cause a dramatic improvement of the response towards H2S gas. The Ag-doped CCTO films were found to be remarkable sensors towards H2S in the concentration range of 0.2–10 ppm. In addition, the response of these sensors towards NH3, H2, NO2 and ethanol vapor was up to two orders of magnitude lower than that for H2S, yielding a highly selective mean of detecting and quantifying H2S. Gas sensing experiments were conducted at operating temperatures ranging from 150 to 350 °C with an optimum response found at 250 °C. In the studied temperature range, Ag-doped CCTO film sensors also showed much shorter response times than that of undoped one. It is found that Ag plays a role promoting the adsorption and catalytic oxidation of H2S leading to drastic changes in the electrical resistance via electron injection into CCTO. © 2017

Registro:

Documento: Artículo
Título:Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films
Autor:Natkaeo, A.; Phokharatkul, D.; Hodak, J.H.; Wisitsoraat, A.; Hodak, S.K.
Filiación:Department of Physics, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand
Carbon-based Devices and Nanoelectronics LaboratoryPathumthani 12120, Thailand
Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina
CONICET – Universidad de Buenos Aires, Instituto de Química-Física de Materiales, Ambientes y Energía (INQUIMAE), Buenos Aires, Argentina
Palabras clave:Ag-doped CaCu3Ti4O12; H2S sensor; Calcium compounds; Catalytic oxidation; Chemical sensors; Cost effectiveness; Deposition; Gas detectors; Semiconductor doping; Silver; Sol-gels; Thin films; Titanium compounds; CaCu3Ti4O12; Concentration ranges; Electrical resistances; Operating temperature; Orders of magnitude; Sensing devices; Sol-gel deposition; Temperature range; Copper compounds
Año:2018
Volumen:260
Página de inicio:571
Página de fin:580
DOI: http://dx.doi.org/10.1016/j.snb.2017.12.134
Título revista:Sensors and Actuators, B: Chemical
Título revista abreviado:Sens Actuators, B Chem
ISSN:09254005
CODEN:SABCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v260_n_p571_Natkaeo

Referencias:

  • Beauchamp, R.O., Bus, J.S., Popp, J.A., Boreiko, C.J., Andjelkovich, D.A., Leber, P., A critical review of the literature on hydrogen sulfide toxicity (1984) CRC Crit. Rev. Toxicol., 13, pp. 25-97
  • Lin, C.-C., Wu, B.-K., Lin, D.-K., Spoilage bacteria in canned foods: I. Flat sour spoilage bacteria in canned asparagus and the thermal death time (1968) Appl. Microbiol., 16, pp. 45-47
  • Nasri, N.S., Jones, J.M., Dupont, V.A., Williams, A., A comparative study of sulfur poisoning and regeneration of precious-metal catalysts (1998) Energy Fuels, 12, pp. 1130-1134
  • Parker, C.D., Mechanics of corrosion of concrete sewers by hydrogen sulfide (1951) Sewage Ind. Wastes, 23, pp. 1477-1485
  • Wells, T., Melchers, R.E., An observation-based model for corrosion of concrete sewers under aggressive conditions (2014) Cem. Concr. Res., 61-62, pp. 1-10
  • Chung, K.F., Hydrogen sulfide as a potential biomarker of asthma (2014) Expert Rev. Respir. Med., 8, pp. 5-13
  • Mathew, T.L., Pownraj, P., Abdulla, S., Pullithadathil, B., Technologies for clinical diagnosis using expired human breath analysis (2015) Diagnostics, 5, pp. 27-60
  • Tesfamichael, T., Arita, M., Bostrom, T., Bell, J., Thin film deposition and characterization of pure and iron-doped electron-beam evaporated tungsten oxide for gas sensors (2010) Thin Solid Films, 518, pp. 4791-4797
  • Phanichphant, S., Semiconductor metal oxides as hydrogen gas sensors (2014) Procedia Eng., 87, pp. 795-802
  • Yin, X.-T., Guo, X.-M., Selectivity and sensitivity of Pd-loaded and Fe-doped SnO2 sensor for CO detection (2014) Sens. Actuators B, 200, pp. 213-218
  • Bai, S., Guo, T., Zhao, Y., Sun, J., Li, D., Chen, A., Sensing performance and mechanism of Fe-doped ZnO microflowers (2014) Sens. Actuators B, 195, pp. 657-666
  • Parra, R., Savu, R., Ramajo, L.A., Ponce, M.A., Varela, J.A., Castro, M.S., Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response (2010) J. Solid State Chem., 183, pp. 1209-1214
  • Li, H.-Y., Yang, H., Guo, X., Oxygen sensors based on SrTi0.65Fe0.35O3-δ thick film with MgO diffusion barrier for automotive emission control (2015) Sens. Actuators B, 213, pp. 102-110
  • Ding, J.-C., Li, H.-Y., Cai, Z.-X., Wang, X.-X., Guo, X., Near room temperature CO sensing by mesoporous LaCoO3 nanowires functionalized with Pd nanodots (2016) Sens. Actuators B, 222, pp. 517-524
  • Pongpaiboonkul, S., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K., Enhancement of H2S-sensing performances with Fe-doping in CaCu3Ti4O12 thin films prepared by a sol–gel method (2016) Sens. Actuators, B, 224, pp. 118-127
  • Huang, H.-M., Li, H.-Y., Wang, X.-X., Guo, X., Detecting low concentration of H2S gas by BaTiO3 nanoparticle-based sensors (2017) Sens. Actuators B, 238, pp. 16-23
  • Hodak, S.K., Supasai, T., Wisitsoraat, A., Hodak, J.H., Design of low cost gas sensor based on SrTiO3 and BaTiO3 films (2010) J. Nanosci. Nanotechnol., 10, pp. 7236-7238
  • Alizadeh, T., Soltani, L.H., Reduced graphene oxide-based gas sensor array for pattern recognition of DMMP vapor (2016) Sens. Actuators B, 234, pp. 361-370
  • Kumar, R., Avasthi, D.K., Kaur, A., Fabrication of chemiresistive gas sensors based on multistep reduced graphene oxide for low parts per million monitoring of sulfur dioxide at room temperature (2017) Sens. Actuators B, 242, pp. 461-468
  • Kwon, Y.J., Na, H.G., Kang, S.Y., Choi, S.-W., Kim, S.S., Kim, H.W., Selective detection of low concentration toluene gas using Pt-decorated carbon nanotubes sensors (2016) Sens. Actuators B, 227, pp. 157-168
  • Mittal, M., Kumar, A., Carbon nanotube (CNT) gas sensors for emissions from fossil fuel burning (2014) Sens. Actuators B, 203, pp. 349-362
  • Hosseini, Z.S., zad, A.I., Mortezaali, A., Room temperature H2S gas sensor based on rather aligned ZnO nanorods with flower-like structures (2015) Sens. Actuators B, 207, pp. 865-871
  • Balamurugan, C., Lee, D.W., Perovskite hexagonal YMnO3 nanopowder as p-type semiconductor gas sensor for H2S detection (2015) Sens. Actuators B, 221, pp. 857-866
  • Feng, L., Wang, Y., Yan, Y., Cao, G., Jiao, Z., Growth of highly-oriented CaCu3Ti4O12 thin films on SrTiO3 (1 0 0) substrates by a chemical solution route (2006) Appl. Surf. Sci., 253, pp. 2268-2271
  • Xu, D., He, K., Yu, R., Jiao, L., Yuan, H., Sun, X., Effect of AETiO3 (AE=Mg, Ca, Sr) doping on dielectric and varistor characteristics of CaCu3Ti4O12 ceramic prepared by the sol–gel process (2014) J. Alloys Compd., 592, pp. 220-225
  • Huang, X., Jiang, Y., Wu, K., CCTO giant dielectric ceramic prepared by reaction sintering (2015) Procedia Eng., 102, pp. 468-474
  • Singh, L., Rai, U.S., Mandal, K.D., Singh, N.B., Progress in the growth of CaCu3Ti4O12 and related functional dielectric perovskites (2014) Prog. Cryst. Growth Charact. Mater., 60, pp. 15-62
  • Yang, W., Yu, S., Sun, R., Du, R., Nano- and microsize effect of CCTO fillers on the dielectric behavior of CCTO/PVDF composites (2011) Acta Mater., 59, pp. 5593-5602
  • Yin, L., Chen, D., Zhang, H., Shao, G., Fan, B., Zhang, R., In situ formation of Au/SnO2 nanocrystals on WO3 nanoplates as excellent gas-sensing materials for H2S detection (2014) Mater. Chem. Phys., 148, pp. 1099-1107
  • Korotcenkov, G., Cho, B.K., Gulina, L.B., Tolstoy, V.P., Gas sensor application of Ag nanoclusters synthesized by SILD method (2012) Sens. Actuators B, 166-167, pp. 402-410
  • Chen, D., Yin, L., Ge, L., Fan, B., Zhang, R., Sun, J., Low-temperature and highly selective NO-sensing performance of WO3 nanoplates decorated with silver nanoparticles (2013) Sens. Actuators B, 185, pp. 445-455
  • Chen, R., Morris, H.R., Whitmore, P.M., Fast detection of hydrogen sulfide gas in the ppmv range with silver nanoparticle films at ambient conditions (2013) Sens. Actuators B, 186, pp. 431-438
  • Lide, D.R., CRC Handbook of Chemistry and Physics (2006), p. 2608. , 87th edition CRC Press/Taylor and Francis Group Boca Raton, FL; Knox, J., Will, H.R., LXXI.-The solubility of silver acetate in acetic acid and of silver propionate in propionic acid (1919) J. Chem. Soc. Trans., 115, pp. 853-854
  • MacDougall, F.H., The solubility of silver acetate in aqueous solutions of silver nitrate and of silver perchlorate. Complex ions formed from silver and acetate ions (1942) J. Phys. Chem., 46, pp. 738-747
  • Kim, I.J., Han, S.D., Han, C.H., Gwak, J., Hong, D.U., Jakhar, D., Development of micro hydrogen gas sensor with SnO2-Ag2O-PtOx composite using MEMS process (2007) Sens. Actuators B, 127, pp. 441-446
  • Pongpaiboonkul, S., Kasa, Y., Phokharatkul, D., Putasaeng, B., Hodak, J.H., Wisitsoraat, A., Controlling the preferential orientation in sol–gel prepared CaCu3Ti4O12 thin films by LaAlO3 and NdGaO3 substrates (2016) Appl. Surf. Sci., 385, pp. 324-332
  • Daniel, L., Nagai, H., Yoshida, N., Sato, M., Photocatalytic activity of vis-responsive Ag-nanoparticles/TiO2 composite thin films fabricated by molecular precursor method (MPM) (2013) Catalysts, 3, pp. 625-645
  • Burrows, N.D., Harvey, S., Idesis, F.A., Murphy, C.J., Understanding the seed-mediated growth of gold nanorods through a fractional factorial design of experiments (2017) Langmuir, 33, pp. 1891-1907
  • Ponce, M.A., Ramirez, M.A., Schipani, F., Joanni, E., Tomba, J.P., Castro, M.S., Electrical behavior analysis of n-type CaCu3Ti4O12 thick films exposed to different atmospheres (2015) J. Eur. Ceram. Soc., 35, pp. 153-161
  • Moreira, M.L., Paris, E.C., do Nascimento, G.S., Longo, V.M., Sambrano, J.R., Mastelaro, V.R., Structural and optical properties of CaTiO3 perovskite-based materials obtained by microwave-assisted hydrothermal synthesis: an experimental and theoretical insight (2009) Acta Mater., 57, pp. 5174-5185
  • Ganesh, I., Gupta, A.K., Kumar, P.P., Sekhar, P.S.C., Radha, K., Padmanabham, G., Preparation and characterization of Ni-Doped TiO2 materials for photocurrent and photocatalytic applications (2012) Sci. World J., 2012, pp. 127326-127341
  • Martina, I., Wiesinger, R., Jembrih-Simb̈rger, D., Schreiner, M., Micro-Raman characterisation of silver corrosion products: instrumental set up and reference database (2012) E-Preserv. Sci.
  • Blanc, J.P., Derouiche, N., El Hadri, A., Germain, J.P., Maleysson, C., Robert, H., Study of the action of gases on a polypyrrole film (1990) Sens. Actuators B, 1, pp. 130-133
  • Capone, P.S.S., Gas sensors from nanostructured metal oxides (2004) Encycl. Nanosci. Nanotechnol., 3, pp. 769-804
  • Franke, M.E.K., Simon, T.J., Metal, U., Metal oxide nanoparticles in chemiresistors: does the nanoscale matter? (2006) Small, 2, pp. 36-50
  • Xu, J., Wang, X., Shen, J., Hydrothermal synthesis of In2O3 for detecting H2S in air (2006) Sens. Actuators B, 115, pp. 642-646
  • Kumar, R., Khanna, A., Sastry, V.S., Interaction of reducing gases with tin oxide films prepared by reactive evaporation techniques (2012) Vacuum, 86, pp. 1380-1386
  • Wei, W., Guo, S., Chen, C., Sun, L., Chen, Y., Guo, W., High sensitive and fast formaldehyde gas sensor based on Ag-doped LaFeO3 nanofibers (2017) J. Alloys Compd., 695, pp. 1122-1127
  • Ma, S., Jia, J., Tian, Y., Cao, L., Shi, S., Li, X., Improved H2S sensing properties of Ag/TiO2 nanofibers (2016) Ceram. Int., 42, pp. 2041-2044
  • Wang, Y., Wang, Y., Cao, J., Kong, F., Xia, H., Zhang, J., Low-temperature H2S sensors based on Ag-doped α-Fe2O3 nanoparticles (2008) Sens. Actuators B, 131, pp. 183-189

Citas:

---------- APA ----------
Natkaeo, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A. & Hodak, S.K. (2018) . Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films. Sensors and Actuators, B: Chemical, 260, 571-580.
http://dx.doi.org/10.1016/j.snb.2017.12.134
---------- CHICAGO ----------
Natkaeo, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. "Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films" . Sensors and Actuators, B: Chemical 260 (2018) : 571-580.
http://dx.doi.org/10.1016/j.snb.2017.12.134
---------- MLA ----------
Natkaeo, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. "Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films" . Sensors and Actuators, B: Chemical, vol. 260, 2018, pp. 571-580.
http://dx.doi.org/10.1016/j.snb.2017.12.134
---------- VANCOUVER ----------
Natkaeo, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. Highly selective sub–10 ppm H2S gas sensors based on Ag-doped CaCu3Ti4O12 films. Sens Actuators, B Chem. 2018;260:571-580.
http://dx.doi.org/10.1016/j.snb.2017.12.134