Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

Canes from Arundo donax, a herbaceous rapid-growing plant, were used as precursor for activated carbon preparation by phosphoric acid activation under a self-generated atmosphere. The influence of the carbonization temperature in the range 400-550°C and of the weight ratio phosphoric acid to precursor (R = 1.5-2.5) on the developed porous structure of the resulting carbons was studied for 1 h of carbonization time. Surface properties of the activated carbons were dependent on a combined effect of the conditions employed. Carbons developed either with R = 1.5 over the range 400-500°C, or with R = 2 at 500°C exhibited surface areas of around 1100 m2/g, the latter conditions promoting a larger pore volume and enhanced mesoporous character. For both ratios, temperature above 500°C led to reduction in porosity development. A similar effect was found for the highest ratio (R = 2.5) and 500°C. The influence of carrying out the carbonization either for times shorter than 1 h or under flowing N2 was also examined at selected conditions (R = 2, 500°C). Shorter times induced increase in the surface area (∼ 1300 m2/g), yielding carbons with smaller mean pore radius. Activated carbons obtained under flowing N2 possessed predominant microporous structures and larger ash contents than the samples derived in the self-generated atmosphere. © 2002 Elsevier Science Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation
Autor:Vernersson, T.; Bonelli, P.R; Cerrella, E.G; Cukierman, A.L
Filiación:Programa de Investigacion y Desarrollo de Fuentes Alternativas de Materias Primas y Energia PINMATE, Depto. de Industrias, Univ. de Buenos Aires, Intendente Guiraldes 2620, Buenos Aires 1428, Argentina
Department of Chemical Engineering and Technology/Chemical Technology, Royal Institute of Technology (KTH), S-100 44 Stockholm, Sweden
Palabras clave:Activated carbons; Arundo donax; Phosphoric acid activation; Pore structure development; Carbon; Carbonization; Phosphoric acid; Porosity; Surface properties; Precursors; Biotechnology; activated carbon; nitrogen; phosphoric acid; activated carbon; phosphonic acid ester; porosity; surface property; vegetation; article; chemical reaction; molecular weight; particle size; plant; porosity; priority journal; synthesis; temperature sensitivity; Adsorption; Biotechnology; Carbon; Carbon Compounds, Inorganic; Kinetics; Microscopy, Electron, Scanning; Nitrogen; Oxygen; Phosphoric Acids; Poaceae; Pressure; Temperature; Time Factors; Arundinaria; Arundo donax; Fraxinus
Año:2002
Volumen:83
Número:2
Página de inicio:95
Página de fin:104
DOI: http://dx.doi.org/10.1016/S0960-8524(01)00205-X
Título revista:Bioresource Technology
Título revista abreviado:Bioresour. Technol.
ISSN:09608524
CODEN:BIRTE
CAS:Carbon Compounds, Inorganic; Carbon, 7440-44-0; Nitrogen, 7727-37-9; Oxygen, 7782-44-7; phosphoric acid, 7664-38-2; Phosphoric Acids
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09608524_v83_n2_p95_Vernersson

Referencias:

  • Antal Jr., M.J., Biomass pyrolysis: A review of the literature. Part 2. Lignocellulose pyrolysis (1982) Advances in Solar Energy, 2. , Boer, K.W., Duffie, J.A. (Eds.). American Solar Energy Society Boulder
  • Bahrton, A., Horowitz, G., Cerrella, G., Bonelli, P., Cassanello, M., Cukierman, A.L., Preparation of activated carbons using poplar wood and bark as precursors (1999) Proceedings of the 4th Biomass Conference of the Americas, pp. 549-554. , Overend, R.P., Chornet, E. (Eds.), Biomass. A Grow Opportunity in Green Energy and Value-added Products. Elsevier, Amsterdam
  • Benaddi, H., Legras, D., Rouzaud, J.N., Beguin, F., Influence of the atmosphere in the chemical activation of wood by phosphoric acid (1998) Carbon, 36, pp. 306-309
  • Blanco Castro, J., Bonelli, P.R., Cerrella, E.G., Cukierman, A.L., Phosphoric acid activation of agricultural residues and bagasse from sugar cane: Influence of the experimental conditions on adsorption characteristics of activated carbons (2000) Ind. Eng. Chem. Res., 39, pp. 4166-4172
  • Bonelli, P.R., Della Rocca, P.A., Cerrella, E.G., Cukierman, A.L., Effect of pyrolysis temperature and thermal degradation rates of Brazil nut shells (2001) Bioresour. Technol., 76, pp. 15-22
  • Cukierman, A.L., Della Rocca, P.A., Bonelli, P.R., Cassanello, M.C., On the study of thermochemical biomass conversion (1996) Trends Chem. Eng., Res. Trends, 3, pp. 129-144
  • Dai, X., Antal Jr., M.J., Synthesis of a high yield activated carbon by air gasification of macadamia nut shell charcoal (1999) Ind. Eng. Chem. Res., 38 (9), pp. 3386-3395
  • Della Rocca, P.A., Cerrella, E.G., Bonelli, P.R., Cukierman, A.L., Pyrolysis of hardwoods residues: On kinetics and chars characterization (1999) Biomass Bioenergy, 16, pp. 79-88
  • Derbyshire, F., Jagtoyen, M., Thwaites, M., Activated carbons - Production and applications (1995) Porosity in Carbons, , Patrick, J.W. (Ed.). Halsted Press, UK (Chapter 9)
  • Faix, O., Meier, D., Beinhoff, O., Analysis of lignocelluloses and lignins from Arundo donax L. and Miscanthus sinensis Anderss, and Hydroliquefaction of Miscanthus (1989) Biomass, 18, pp. 109-126
  • Gergova, K., Galushko, A., Petrov, N., Minkova, V., Investigation of the porous structure of activated carbons prepared by pyrolysis of agricultural by-products in a stream of water vapour (1992) Carbon, 30 (5), pp. 721-727
  • Girgis, B.S., Khalil, L.B., Tawfik, T.A.M., Activated carbon from sugar cane bagasse by carbonization in the presence of inorganic acids (1994) J. Chem. Technol. Biotechnol., 69, pp. 87-92
  • Girgis, B.S., Ishak, M.F., Activated carbon from cotton stalks by impregnation with phosphoric acid (1999) Mater. Lett., 39, pp. 107-114
  • Gregg, S.J., Sing, K.S.W., (1982) Adsorption, Surface Area and Porosity, second ed., , Academic Press, London
  • Heschel, W., Klose, E., On the suitability of agricultural by-products for the manufacture of granular activated carbon (1995) Fuel, 74 (12), pp. 1786-1791
  • Horowitz, G.I., Lombardi, G., Cassanello, M.C., Cukierman, A.L., Gasification of an agricultural by-product: A study towards activated carbons preparation (1997) Proceedings of the 4th Asian Pacific International Symposium on Combustion and Energy Utilization, pp. 757-761. , Chulalongkorn University, Bangkok
  • Jagtoyen, M., Derbyshire, F., Activated carbons from yellow poplar and white oak by H3PO4 activation (1998) Carbon, 36, pp. 1085-1097
  • Khalili, N., Pan, M., Sandi, G., Determination of fractal dimensions of solid carbons from gas and liquid phase adsorption isotherms (2000) Carbon, 38, pp. 573-588
  • Kyotani, T., Control of pore structure (2000) Carbon, 38, pp. 269-286
  • Laine, J., Calafat, A., Labady, M., Preparation and characterization of activated carbons from coconut shell impregnated with phosphoric acid (1989) Carbon, 27, pp. 191-195
  • Laine, J., Yunes, S., Effect of the preparation method on the pore size distribution of activated carbon from coconut shell (1992) Carbon, 30 (4), pp. 601-604
  • Molina-Sabio, M., Rodríguez-Reinoso, F., Caturla, F., Sellés, M.J., Porosity in granular carbons activated with phosphoric acid (1995) Carbon, 33, pp. 1105-1113
  • Patrick, J.W., (1995) Porosity in Carbons, , Halsted Press, UK
  • Pendyal, B., Johns, M.M., Marshall, W.E., Ahmedna, M., Rao, R.M., The effect of binders and agricultural by-products on physical and chemical properties of granular activated carbons (1999) Bioresour. Technol., 68 (3), pp. 247-254
  • Philip, C.A., Girgis, B.S., Adsorption characteristics of microporous carbons from apricot stones activated by phosphoric acid (1996) J. Chem. Technol. Biotechnol., 67, pp. 248-254
  • Shafizadeh, F., Chin, P.P.S., Thermal deterioration of wood, wood technology, chemical aspects (1977) ACS Symp. Series, 43, pp. 57-81
  • Solum, M.S., Pugmire, R.J., Jagtoyen, M., Derbyshire, F., Evolution of carbon structure in chemically activated wood (1995) Carbon, 33 (9), pp. 1247-1254
  • Szabó, P., Várhegyi, G., Till, F., Faix, O., Thermogravimetric/mass spectrometric characterization of two energy crops, Arundo donax and Miscanthus sinensis (1996) J. Ann. Appl. Pyrolysis, 36, pp. 179-190
  • Tancredi, N., Cordero, T., Rodríguez-Mirasol, J., Rodríguez, J., Activated carbons from Uruguayan eucalyptus wood (1996) Fuel, 75 (15), pp. 1701-1706
  • Teng, H., Yeh, T.S., Preparation of activated carbons from bituminous coals with zinc chloride activation (1998) Ind. Eng. Chem. Res., 37, pp. 58-65
  • Toles, C., Rimmer, S., Hower, J.C., Production of activated carbons from a Washington lignite using phosphoric acid activation (1996) Carbon, 34 (11), pp. 1419-1426
  • Toles, C., Marshall, W., Johns, M., Surface functional groups on acid-activated nutshells carbons (1999) Carbon, 37, pp. 1207-1214
  • Toles, C., Marshall, W., Johns, M., Wartelle, L., McAloon, A., Acid-activated carbons from almond shells: Physical, chemical and adsorptive properties and estimated cost of production (2000) Bioresour. Technol., 71, pp. 87-92

Citas:

---------- APA ----------
Vernersson, T., Bonelli, P.R, Cerrella, E.G & Cukierman, A.L (2002) . Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation. Bioresource Technology, 83(2), 95-104.
http://dx.doi.org/10.1016/S0960-8524(01)00205-X
---------- CHICAGO ----------
Vernersson, T., Bonelli, P.R, Cerrella, E.G, Cukierman, A.L "Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation" . Bioresource Technology 83, no. 2 (2002) : 95-104.
http://dx.doi.org/10.1016/S0960-8524(01)00205-X
---------- MLA ----------
Vernersson, T., Bonelli, P.R, Cerrella, E.G, Cukierman, A.L "Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation" . Bioresource Technology, vol. 83, no. 2, 2002, pp. 95-104.
http://dx.doi.org/10.1016/S0960-8524(01)00205-X
---------- VANCOUVER ----------
Vernersson, T., Bonelli, P.R, Cerrella, E.G, Cukierman, A.L Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation. Bioresour. Technol. 2002;83(2):95-104.
http://dx.doi.org/10.1016/S0960-8524(01)00205-X