Authors: | Alashkar, Nour Arca, Massimiliano Alnasr, Hazem Lutter, Michael Lippolis, Vito |
Title: | Water-soluble organotin compounds |
Other Titles: | syntheses, structures and reactivity towards fluoride anion in water |
Language (ISO): | en |
Abstract: | Herein, we report the syntheses of the water-soluble organotin compounds [{Me2(H)N(CH2)3}2SnX2]Y2 (1, X = Cl, Y = ClO4; 2, X = F, Y = ClO4) and {Me2(H)N(CH2)3}2SnX4 (3, X = Cl; 4, X = F). The compounds were characterized by elemental analysis, electrospray mass spectrometry, 1H, 13C, 19F, and 119Sn NMR spectroscopy, and in the case of compounds 1, 3 and 4, by single-crystal X-ray diffraction analysis. The reaction of compound 2 with fluoride anions in water was investigated by NMR spectroscopy. DFT calculations accompany the experimental work. |
Subject Headings: | Tin Fluorides Cations Lewis acids Structure elucidation Density functional calculations |
URI: | http://hdl.handle.net/2003/40328 http://dx.doi.org/10.17877/DE290R-22203 |
Issue Date: | 2020-08-21 |
Rights link: | https://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Lehrstühle für Anorganische Chemie |
Files in This Item:
File | Description | Size | Format | |
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ejic.202000665.pdf | 2.09 MB | Adobe PDF | View/Open |
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