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Sustainability of the Catalytic Activity of a Silica-Titania Composite (STC) for Long-Term Indoor Air Quality ControlTiO2-assisted photocatalytic oxidation (PCO) is an emerging technology for indoor air quality control and is also being evaluated as an alternative trace contaminant control technology for crew habitats in space exploration. Though there exists a vast range of literature on the development of photocatalysts and associated reactor systems, including catalyst performance and performance-influencing factors, the critical question of whether photocatalysts can sustain their initial catalytic activity over an extended period of operation has not been adequately addressed. For a catalyst to effectively serve as an air quality control product, it must be rugged enough to withstand exposure to a multitude of low concentration volatile organic compounds (VOCs) over long periods of time with minimal loss of activity. The objective of this study was to determine the functional lifetime of a promising photocatalyst - the silica-titania composite (STC) from Sol Gel Solutions, LLC in a real-world scenario. A bench-scale STC-packed annular reactor under continuous irradiation by a UV-A fluorescent black-light blue lamp ((lambda)max = 365 nm) was exposed to laboratory air continuously at an apparent contact time of 0.27 sand challenged with a known concentration of ethanol periodically to assess any changes in catalytic activity. Laboratory air was also episodically spiked with halocarbons (e.g., octafluoropropane), organosulfur compounds (e.g., sulfur hexafluoride), and organosilicons (e.g., siloxanes) to simulate accidental releases or leaks of such VOCs. Total organic carbon (TOC) loading and contaminant profiles of the laboratory air were also monitored. Changes in STC photocatalytic performance were evaluated using the ethanol mineralization rate, mineralization efficiency, and oxidation intermediate (acetaldehyde) formation. Results provide insights to any potential catalyst poisoning by trace halocarbons and organosulfur compounds.
Document ID
20120000407
Acquisition Source
Kennedy Space Center
Document Type
Conference Paper
Authors
Coutts, Janelle L. (University of Central Florida Orlando, FL, United States)
Levine, Lanfang H. (Enterprise Advisory Services, Inc. Houston, TX, United States)
Richards, Jeffrey T. (Stinger Ghaffarian Technologies, Inc. (SGT, Inc.) Kennedy Space Center, FL, United States)
Date Acquired
August 25, 2013
Publication Date
January 1, 2011
Subject Category
Chemistry And Materials (General)
Report/Patent Number
KSC-2011-300
Meeting Information
Meeting: 42nd International Conference on Environmental Systems (ICES)
Location: San Diego, CA
Country: United States
Start Date: July 15, 2012
End Date: July 19, 2012
Funding Number(s)
CONTRACT_GRANT: NNK11EA09C
Distribution Limits
Public
Copyright
Public Use Permitted.

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